66737-07-3

Basic information

• Product Name: 1-(4-methoxycarbonylphenyl)-3-phenylpropynone
• Synonyms: 1-(4-methoxycarbonylphenyl)-3-phenylpropynone
• CAS NO: 66737-07-3
• Molecular Weight: 264.28
• Mol File: 66737-07-3.mol
• Article Data: 20

Chemical Properties

• CAS DataBase Reference: 1-(4-methoxycarbonylphenyl)-3-phenylpropynone(CAS DataBase Reference)
• NIST Chemistry Reference: 1-(4-methoxycarbonylphenyl)-3-phenylpropynone(66737-07-3)
• EPA Substance Registry System: 1-(4-methoxycarbonylphenyl)-3-phenylpropynone(66737-07-3)

Safety Data

• Hazardous Substances Data: 66737-07-3(Hazardous Substances Data)

Upstream product

• 21928-11-0 methyl 4-(dimethylcarbamoyl)benzoate 
• 536-74-3 phenylacetylene 
• 201230-82-2 carbon monoxide 
• 619-44-3 methyl 4-iodobenzoate 
• 7377-26-6 4-Methoxycarbonylbenzoyl chloride 
• 637-44-5 phenylpropyolic acid 
• 619-45-4 4-methoxycarbonyl aniline 
• 77726-96-6 methyl 4-(3,3-diethyltriaz-1-en-1-yl)benzoate 
• 64-18-6 formic acid 
• 7436-90-0 2,2-dibromostyrene 
• 100-52-7 benzaldehyde 
• 360789-45-3 4-Methoxycarbonyl-α-oxo-benzeneacetic acid 
• 3609-53-8 methyl 4-acetylbenzoate 
• 1679-64-7 Monomethyl terephthalate 

Downstream Products

• 42497-80-3 methyl 4-(phenylethynyl)benzoate 
• 86235-82-7 1-(4′-carbomethoxyphenyl)-3-phenyl-1,3-propanedione 

Relevant articles and documents

Bifunctional Borane Catalysis of a Hydride Transfer/Enantioselective [2+2] Cycloaddition Cascade

Herein, we present a mild and efficient method for synthesizing enantioenriched tetrahydroquinoline-fused cyclobutenes through a cascade reaction between 1,2-dihydroquinolines and alkynones with catalysis by chiral spiro-bicyclic bisboranes. The bisborane

Recyclable heterogeneous palladium-catalyzed carbonylative Sonogashira coupling under CO gas-free conditions

A convenient, efficient and practical heterogeneous palladium-catalyzed carbonylative Sonogashira coupling of aryl iodides with terminal alkynes under CO gas-free conditions has been developed by using an MCM-41-supported bidentate phosphine palladium ace

Regio- and Stereoselective Hydrosulfonylation of Electron-Deficient Alkynes: Access to Both E- and Z-β-Sulfonyl-α,β-Unsaturated Carbonyl Compounds

A metal-free hydrosulfonylation of electron-deficient alkynes with sodium sulfinates or sulfinic acids to access both E- and Z-β-sulfonyl-α,β-unsaturated carbonyl compounds has been developed. We propose that this reaction via a hydroxylallene intermediate delivers the thermodynamically stable E isomer, or via a concerted termolecular AdE3 mechanism affords Z isomer. The stereoselectivity of addition (syn or anti) can be controlled by varying the sulfonyl sources and acidic buffer solutions. This protocol exhibits broad substrate scope for internal or terminal alkynes including various substituted ynones and alkynyl esters. This approach is mild, efficient, operationally simple and easy to be scaled-up. (Figure presented.).