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  • 659-28-9 Structure
  • Basic information

    1. Product Name: 4-(Trifluoromethoxy)benzaldehyde
    2. Synonyms: α,α,α-trifluoroanisaldehyde;4-(Trifluoromethoxy)benzaldehyde 98%;4-(Trifluoromethoxy)benzaldehyde98%;Benzaldehyde, 4-(trifluoromethoxy)-;4-(Trifluoromethoxy)benzaldehyde,99%;On trifluoroMethoxy benzaldehyde;4-(TRIFLUOROMETHOXY)BENZALDEHYDE FOR SYN;For trifluoromethoxy benzaldehyde
    3. CAS NO:659-28-9
    4. Molecular Formula: C8H5F3O2
    5. Molecular Weight: 190.12
    6. EINECS: 211-531-4
    7. Product Categories: Trifluoroanisole series;Aromatic Aldehydes & Derivatives (substituted);Benzaldehyde;Benzaldehyde series;Pyridines
    8. Mol File: 659-28-9.mol
    9. Article Data: 15
  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: 93 °C27 mm Hg(lit.)
    3. Flash Point: 159 °F
    4. Appearance: Clear colorless to pale yellow-green/Liquid
    5. Density: 1.331 g/mL at 25 °C(lit.)
    6. Vapor Pressure: 0.438mmHg at 25°C
    7. Refractive Index: n20/D 1.458(lit.)
    8. Storage Temp.: Store below +30°C.
    9. Solubility: N/A
    10. Sensitive: Air Sensitive
    11. BRN: 1949135
    12. CAS DataBase Reference: 4-(Trifluoromethoxy)benzaldehyde(CAS DataBase Reference)
    13. NIST Chemistry Reference: 4-(Trifluoromethoxy)benzaldehyde(659-28-9)
    14. EPA Substance Registry System: 4-(Trifluoromethoxy)benzaldehyde(659-28-9)
  • Safety Data

    1. Hazard Codes: Xi,Xn
    2. Statements: 36/37/38-36/38-22
    3. Safety Statements: 26-36/37/39-37/39
    4. WGK Germany: 3
    5. RTECS:
    6. HazardClass: IRRITANT
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 659-28-9(Hazardous Substances Data)

659-28-9 Usage

Description

4-(Trifluoromethoxy)benzaldehyde, also known as p-(trifluoromethoxy)benzaldehyde, is an aromatic aldehyde characterized by its clear colorless to pale yellow-green liquid appearance. It is a key intermediate in the synthesis of various organic compounds and dyes, making it a valuable component in the chemical industry.

Uses

Used in Pharmaceutical Industry:
4-(Trifluoromethoxy)benzaldehyde is used as a synthetic intermediate for the development of new pharmaceutical compounds, such as (E)-4-(trifluoromethoxy)benzaldehyde thiosemicarbazone, which may have potential applications in the medical field.
Used in Dye Industry:
In the dye industry, 4-(Trifluoromethoxy)benzaldehyde is used as a starting material for the synthesis of new azo dyes containing a 5(4H)-oxazolone ring. These dyes can be utilized in various applications, such as textiles, plastics, and printing inks.
Used in Chemical Synthesis:
4-(Trifluoromethoxy)benzaldehyde is used as a building block in the synthesis of various organic compounds, including 2-[4-(trifluoromethoxy)phenyl]-1H-benzimidazole and (E)-2-[4-(trifluoromethoxy)benzylidene]indan-1-one. These compounds can be further utilized in the development of new materials and products across different industries.
Used in Research and Development:
Due to its unique chemical properties and reactivity, 4-(Trifluoromethoxy)benzaldehyde is also used in research and development for the exploration of new chemical reactions and the creation of novel compounds with potential applications in various fields.

Check Digit Verification of cas no

The CAS Registry Mumber 659-28-9 includes 6 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 3 digits, 6,5 and 9 respectively; the second part has 2 digits, 2 and 8 respectively.
Calculate Digit Verification of CAS Registry Number 659-28:
(5*6)+(4*5)+(3*9)+(2*2)+(1*8)=89
89 % 10 = 9
So 659-28-9 is a valid CAS Registry Number.
InChI:InChI=1/C8H5F3O2/c9-8(10,11)13-7-3-1-6(5-12)2-4-7/h1-5H

659-28-9 Well-known Company Product Price

  • Brand
  • (Code)Product description
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  • TCI America

  • (T2256)  4-(Trifluoromethoxy)benzaldehyde  >97.0%(GC)

  • 659-28-9

  • 5g

  • 580.00CNY

  • Detail
  • TCI America

  • (T2256)  4-(Trifluoromethoxy)benzaldehyde  >97.0%(GC)

  • 659-28-9

  • 25g

  • 1,750.00CNY

  • Detail
  • Alfa Aesar

  • (A10671)  4-(Trifluoromethoxy)benzaldehyde, 96%   

  • 659-28-9

  • 5g

  • 673.0CNY

  • Detail
  • Alfa Aesar

  • (A10671)  4-(Trifluoromethoxy)benzaldehyde, 96%   

  • 659-28-9

  • 25g

  • 3363.0CNY

  • Detail

659-28-9SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 12, 2017

Revision Date: Aug 12, 2017

1.Identification

1.1 GHS Product identifier

Product name 4-(Trifluoromethoxy)benzaldehyde

1.2 Other means of identification

Product number -
Other names 4-trifluoromethoxybenzaldehyde

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:659-28-9 SDS

659-28-9Relevant articles and documents

Mild oxidation of benzyl alcohols to benzyl aldehydes or ketones catalyzed by visible light

Cheng, Dongping,Li, Xiaonian,Ren, Shujian,Xu, Xiaoliang

supporting information, (2021/07/02)

Induced by visible light, mild oxidation condition to prepare benzyl aldehydes or ketones have been developed by using bromotrichloromethane as photochemical oxidant. This method avoids high temperature, pressure and peroxidation with only visible light as the green driving force.

Photocatalytic trifluoromethoxylation of arenes and heteroarenes in continuous-flow

Cendón, Borja,Gulías, Moisés,Ho, Michelle,No?l, Timothy,Nyuchev, Alexander V.,Sambiagio, Carlo,Struijs, Job J. C.,Wan, Ting,Wang, Ying

supporting information, p. 1305 - 1312 (2020/07/10)

The first example of photocatalytic trifluoromethoxylation of arenes and heteroarenes under continuous-flow conditions is described. Application of continuous-flow microreactor technology allowed to reduce the residence time up to 16 times in comparison t

TEMPO-mediated oxidation of primary alcohols to aldehydes under visible light and air

Liu, Dongwang,Zhou, Hongxia,Gu, Xiangyong,Shen, Xiaoqin,Li, Pixu

supporting information, p. 117 - 122 (2014/03/21)

A homogeneous visible light photoredox TEMPO-mediated selective oxidation of primary alcohols to the corresponding carbonyl compounds was developed using molecular oxygen from air as the terminal oxidant. Ru(bpy)3(PF 6)2 (bpy: bipyridyl) and Ir(dtb-bpy)(ppy) 2(PF6) (dtb-bpy: 4,4′-di-tert-butyl-2,2′- bipyridyl; ppy: 2-phenylpyridine) were used as the sensitizers. A homogeneous visible light photoredox TEMPO-mediated selective oxidation of primary alcohols to the corresponding carbonyl compounds was developed. Molecular oxygen from air was the terminal oxidant. Copyright

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