64268-27-5Relevant articles and documents
A novel synthesis of 4B-element-containing styrene derivatives
Nagasaki, Yukio,Kurosawa, Koichi,Tsuruta, Teiji
, p. 3036 - 3038 (2007/10/02)
To synthesize 4B-group element-containing styrene monomers, alkylmetalation reactions of 4-methylstyrene (1) in the presence of lithium diisopropylamide (2) were investigated. Trialkylsilylation of 1 proceeded easily by the reaction with trialkylsilyl chloride in the presence of 2 to form mono- and bis-trialkylsilylated methylstyrene. This synthetic method was expanded to other 4B-elementcontaining styrenes such as germyl and stannyl compounds.