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63444-51-9

6-Methoxy-2-vinylnaphthalene is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

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  • 63444-51-9 Structure

  • Basic information

    1. Product Name: 6-Methoxy-2-vinylnaphthalene
    2. Synonyms: 6-METHOXY-2-VINYLNAPHTHALENE;6-Methoxy-2-vinylnaphthalene, 97+%;2-methoxy-6-vinylnaphthalene;6-METHOXY-2-VINYLINSPHTHOLENE;6-Methoxy-2-naphthylethylene;2-ethenyl-6-Methoxynaphthalene
    3. CAS NO:63444-51-9
    4. Molecular Formula: C13H12O
    5. Molecular Weight: 184.23
    6. EINECS: 200-110-4
    7. Product Categories: Heterocyclic Compounds;API;Benzenes
    8. Mol File: 63444-51-9.mol
    9. Article Data: 4

  • Chemical Properties

    1. Melting Point: 88-91 °C
    2. Boiling Point: 278.19°C (rough estimate)
    3. Flash Point: 122.7 °C
    4. Appearance: /
    5. Density: 1.0120 (rough estimate)
    6. Vapor Pressure: 0.00091mmHg at 25°C
    7. Refractive Index: 1.5928 (estimate)
    8. Storage Temp.: Sealed in dry,Store in freezer, under -20°C
    9. Solubility: N/A
    10. CAS DataBase Reference: 6-Methoxy-2-vinylnaphthalene(CAS DataBase Reference)
    11. NIST Chemistry Reference: 6-Methoxy-2-vinylnaphthalene(63444-51-9)
    12. EPA Substance Registry System: 6-Methoxy-2-vinylnaphthalene(63444-51-9)

  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: 24/25
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 63444-51-9(Hazardous Substances Data)

63444-51-9 Usage

Chemical Properties

Beige crystalline powder

Check Digit Verification of cas no

The CAS Registry Mumber 63444-51-9 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 6,3,4,4 and 4 respectively; the second part has 2 digits, 5 and 1 respectively.
Calculate Digit Verification of CAS Registry Number 63444-51:
(7*6)+(6*3)+(5*4)+(4*4)+(3*4)+(2*5)+(1*1)=119
119 % 10 = 9
So 63444-51-9 is a valid CAS Registry Number.
InChI:InChI=1/C13H12O/c1-3-10-4-5-12-9-13(14-2)7-6-11(12)8-10/h3-9H,1H2,2H3

63444-51-9SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 15, 2017

Revision Date: Aug 15, 2017

1.Identification

1.1 GHS Product identifier

Product name 2-Methoxy-6-vinylnaphthalene

1.2 Other means of identification

Product number -
Other names 2-ethenyl-6-Methoxynaphthalene

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:63444-51-9 SDS

63444-51-9Relevant articles and documents

Oxidations of allylic and benzylic alcohols under inductively-heated flow conditions with gold-doped superparamagnetic nanostructured particles as catalyst and oxygen as oxidant

Chaudhuri, Sangeeta Roy,Hartwig, Jan,Kupracz, Lukas,Kodanek, Torben,Wegner, Jens,Kirschning, Andreas

supporting information, p. 3530 - 3538 (2015/02/19)

A continuous flow protocol for the oxidation of allylic and benzylic alcohols to aldehydes and ketones, respectively, using oxygen gas or atmospheric air is reported. The key features of this work are gold nanoparticles that are attached to the surface of nanostructured core shell particles composed of an Fe3O4-containing core and a silica shell. These nanostructured particles exert superparamagnetic properties and thus inductively heat up in an external oscillating electromagnetic field, conditions under which the gold catalyst is able to perform these oxidation reactions.

Fe-promoted cross coupling of homobenzylic methyl ethers with Grignard reagents via sp3 C-O bond cleavage

Luo, Shuang,Yu, Da-Gang,Zhu, Ru-Yi,Wang, Xin,Wang, Lei,Shi, Zhang-Jie

supporting information, p. 7794 - 7796 (2013/09/02)

The first iron-catalyzed formal cross coupling of homobenzylic methyl ethers with alkyl Grignard reagents is realized. The reaction is proposed to proceed through a sequence of dehydroalkoxylation to form the vinyl-intermediate, followed by Fe-catalyzed selective carbometalation to form a benzylic Grignard reagent.

Suzuki cross-coupling reactions between alkenylboronic acids and aryl bromides catalysed by a tetraphosphane-palladium catalyst

Peyroux, Eugenie,Berthiol, Florian,Doucet, Henri,Santelli, Maurice

, p. 1075 - 1082 (2007/10/03)

A range of alkenylboronic acids undergo Suzuki cross-coupling with aryl bromides in good yields in the presence of [PdCl(C3H 5)]2/cis,cis,cis-1,2,3,4-tetrakis[(diphenylphosphanyl) methyl]cyclopentane as a catalyst. A wide variety of 1-arylprop-1-enes, 2-arylprop-1-enes, 2-arylbut-1-enes and 1,1-diarylethylene or styrene derivatives have been prepared. Moreover, the reaction tolerates several functions, such as acetyl, formyl, nitrile or nitro. Furthermore, this catalyst can be used at low loading, even for reactions of sterically hindered substrates. Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004.

HYDROFORMYLATION CATALYSED BY RHODIUM COMPLEXES OF TREHALOSE-DERIVED LIGANDS αα and ββ-TREDIP; A HIGHLY REGIOSELECTIVE ROUTE TO α-METHYLARYLPROPIONALDEHYDES

Brown, John M.,Cook, Stephen J.,Khan, Riaz

, p. 5105 - 5110 (2007/10/02)

Rhodium complexes of the ligand αα-TREDIP give 62:1 iso-regioselectivity in the hydroformylation of styrene under ambient conditions without excess posphine, higher than any previously reported value.The results are compared with those obtained with other ligands, and extended to preparation of 2-(6-methoxy-2-naphthyl)-propanal, a precursor of the anti-inflammatory drug naproxen.

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