629-82-3Relevant articles and documents
Herriott,Picker
, p. 4521,4522, 4523 (1972)
Synthesis and characterization of a well-defined carbon nanohorn- supported molybdenum dioxo catalyst by SMART-EM imaging. surface structure at the atomic level
Kratish, Yosi,Nakamuro, Takayuki,Liu, Yiqi,Li, Jiaqi,Tomotsuka, Issei,Harano, Koji,Nakamura, Eiichi,Marks, Tobin J.
supporting information, p. 427 - 432 (2021/03/15)
The molybdenum dioxo catalyst CNH/MoO2 is prepared via direct grafting of (dme)MoO2Cl2 (dme = 1,2-dimethoxyethane) onto the graphitic surfaces of carbon nanohorn (CNH) substrates. The structure of this heterogeneous catalyst was characterized by SMART-EM, XPS, and ICP, and is found to have single isolated MoO2 species on the surface as well as a few multi-Mo species. The CNH/MoO2 complex exhibits excellent catalytic activity for polyethylene terephthalate (PET) hydrogenolysis, N-oxide reductions, and reductive carbonyl coupling, representing an informative model catalyst for structural and mechanistic investigations.
METHOD FOR PRODUCING ALIPHATIC LINEAR PRIMARY ALCOHOLS
-
, (2020/05/06)
Provided are a method of preparing a linear primary alcohol, a catalyst for converting an α-olefin into an alcohol, and a method of converting an α-olefin into a linear primary alcohol, and the method of preparing a linear primary alcohol according to the present invention includes: charging a reactor with a heterogeneous catalyst including a cobalt oxide and a Cn olefin (S1); bringing the heterogeneous catalyst including a cobalt oxide into contact with the Cn olefin (S2); and supplying the reactor with a synthetic gas to obtain a Cn+1 alcohol (S3).