6281-14-7Relevant articles and documents
One-pot catalytic synthesis of 2,7-bis-substituted 4,9(10)-dimethyl-2,3a,5a,7,8a,10a-hexaazaperhydropyrenes
Rakhimova, Elena B.,Kirsanov, Victor Yu.,Meshcheryakova, Ekaterina S.,Khalilov, Leonard M.,Kutepov, Boris I.,Ibragimov, Askhat G.,Dzhemilev, Usein M.
, p. 6880 - 6886 (2017)
Catalytic methods for the synthesis of 2,7-bis-substituted 4,9(10)-dimethyl-2,3a,5a,7,8a,10a-hexaazaperhydropyrenes have been developed. The structure was established on the basis of 1H and 13C NMR spectra, 2D NMR (HSQC, HMBC, COSY, NOESY) techniques, MALDI TOF/TOF spectra, and X-ray diffraction data. Primary screening of the synthesized hexaazaperhydropyrenes for antimicrobial activity was performed.
Synthesis and Crystal Structure of Dipotassium Salts of N-Alkyl-N-{[O-alkoxy(hydroxy)phosphoryl]methyl}ditiocarbamic Acids
Garifzyanov, A. R.,Islamov, D. R.,Mirzayanov, I. I.,Shtyrlin, V. G.
, p. 381 - 384 (2020/04/27)
Abstract: A one-pot method for the synthesis of dipotassium salts of N-alkyl-N-{[O-alkoxy(hydroxy)phosphoryl]methyl}dithiocarbamic acids has been elaborated. Dipotassium salts of N-isopropyl-, N-butyl-, and N-cyclohexyl-N-{[hydroxy(O-ethoxy)phosphoryl]methyl}dithiocarbamic acids as well as N-{[O-butoxy(hydroxy)phosphoryl]methyl}-N-(2-methoxyethyl)dithiocarbamic acid have been synthesized and isolated. Crystal and molecular structure of the latter compound have been elucidated.
First Synthesis of 2,9-Disubstituted cis-2,3a,7b,9,10a,14b- Hexaazaperhydrodibenzotetracenes
Rakhimova, Elena B.,Kirsanov, Victor Yu.,Mescheryakova, Ekaterina S.,Khalilov, Leonard M.,Ibragimov, Askhat G.,Dzhemilev, Usein M.
, p. 1861 - 1866 (2018/07/21)
The first synthesis of 2,9-disubstituted cis-2,3a,7b,9,10a,14b-hexaazaperhydrodibenzotetracenes has been accomplished through intermolecular heterocyclization of N, N -bis(methoxymethyl)alkylamines with cis -1,6,7,12-tetraazaperhydrotetracene in the presence of SmCl 3 ·6H 2 O catalyst or by recyclization of 1,3,5-tricycloalkyl-1,3,5-triazinanes with cis -1,6,7,12-tetraazaperhydrotetracene in the presence of NiCl 2 ·6H 2 O catalyst. The structures were established by 1D (1 H, and 13 C) and 2D (HSQC, HMBC, COSY, NOESY) NMR spectroscopy, MALDI TOF/TOF mass spectrometry, and X-ray diffraction analyses.