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6163-64-0

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6163-64-0 Usage

Description

TERT-BUTYL METHYL SULFIDE is a clear colorless liquid that has been reported to undergo enantioselective oxidation when catalyzed by an alloxazine-cyclodextrin conjugate. It is characterized by its high sulfur content, which makes it a valuable compound in various industrial applications.

Uses

Used in LPG Refining Process:
TERT-BUTYL METHYL SULFIDE is used as a refining agent in the liquefied petroleum gas (LPG) industry for its high sulfur content. The application reason is to improve the quality of LPG by reducing the sulfur content, which can lead to cleaner burning and reduced emissions.
Used in Chemical Synthesis:
TERT-BUTYL METHYL SULFIDE can be used as a reagent or intermediate in the synthesis of various organic compounds due to its unique chemical properties. The application reason is its ability to participate in enantioselective oxidation reactions, which can be crucial for the production of specific enantiomers with desired biological activities.
Used in Analytical Chemistry:
TERT-BUTYL METHYL SULFIDE may also find use in analytical chemistry as a reference compound or standard for the development and validation of analytical methods. The application reason is its distinct chemical properties, which can help in the accurate determination of other compounds in complex mixtures.

Check Digit Verification of cas no

The CAS Registry Mumber 6163-64-0 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 6,1,6 and 3 respectively; the second part has 2 digits, 6 and 4 respectively.
Calculate Digit Verification of CAS Registry Number 6163-64:
(6*6)+(5*1)+(4*6)+(3*3)+(2*6)+(1*4)=90
90 % 10 = 0
So 6163-64-0 is a valid CAS Registry Number.
InChI:InChI=1/C5H12S/c1-5(2,3)6-4/h1-4H3

6163-64-0 Well-known Company Product Price

  • Brand
  • (Code)Product description
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  • Packaging
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  • Alfa Aesar

  • (B22390)  tert-Butyl methyl sulfide, 98+%   

  • 6163-64-0

  • 5g

  • 394.0CNY

  • Detail
  • Alfa Aesar

  • (B22390)  tert-Butyl methyl sulfide, 98+%   

  • 6163-64-0

  • 25g

  • 817.0CNY

  • Detail
  • Aldrich

  • (294012)  tert-Butylmethylsulfide  97%

  • 6163-64-0

  • 294012-5ML

  • 548.73CNY

  • Detail
  • Aldrich

  • (294012)  tert-Butylmethylsulfide  97%

  • 6163-64-0

  • 294012-25ML

  • 2,015.91CNY

  • Detail

6163-64-0SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 12, 2017

Revision Date: Aug 12, 2017

1.Identification

1.1 GHS Product identifier

Product name 2-Methyl-2-(methylthio)propane

1.2 Other means of identification

Product number -
Other names t-butyl methyl sulfide

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:6163-64-0 SDS

6163-64-0Relevant articles and documents

Carbon-sulfur bond-forming reductive elimination involving sp-, sp2-, and sp3-hybridized carbon. Mechanism, steric effects, and electronic effects on sulfide formation

Mann, Grace,Baranano, David,Hartwig, John F.,Rheingold, Arnold L.,Guzei, Ilia A.

, p. 9205 - 9219 (2007/10/03)

Palladium thiolato complexes [(L)Pd(R)(SR')], within which L is a chelating ligand such as DPPE, DPPP, DPPBz, DPPF, or TRANSPHOS, R is a methyl, alkenyl, aryl, or alkynyl ligand, and R' is an aryl or alkyl group, were synthesized by substitution or proton-transfer reactions. All of these thiolato complexes were found to undergo carbon-sulfur bond-forming inductive elimination in high yields to form dialkyl sulfides, diaryl sulfides, alkyl aryl sulfides, alkyl alkenyl sulfides, and alkyl alkynyl sulfides. Reductive eliminations forming alkenyl alkyl sulfides and aryl alkyl sulfides were the fastest. Eliminations of alkynyl alkyl sulfides were slower, and elimination of dialkyl sulfide was the slowest. Thus the relative rates for sulfide elimination as a function of the hybridization of the palladium-bound carbon follow the trend sp2 > sp >> sp3. Rates of reductive elimination were faster for cis-chelating phosphine ligands with larger bite angles. Kinetic studies, along with results from radical trapping reactions, analysis of solvent effects; and analysis of complexes with chelating phosphines of varying rigidity, were conducted with [Pd(L)(S-tert-butyl)(Ar)] and [Pd(L)(S- tert-butyl)(Me)]. Carbon-sulfur bond-forming reductive eliminations involving both saturated and unsaturated hydrocarbyl groups proceed by an intramolecular, concerted mechanism. Systematic changes in the electronic properties of the thiolate and aryl groups showed that reductive elimination is the fastest for electron deficient aryl groups and electron rich arenethiolates, suggesting that the reaction follows a mechanism in which the thiolate acts as a nucleophile and the aryl group an electrophile. Studies with thiolate ligands and hydrocarbyl ligands of varying steric demands favor a migration mechanism involving coordination of the hydrocarbyl ligand in the transition state.

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