61130-14-1Relevant articles and documents
Palladium(0)-catalyzed arylative dearomatization of phenols
Rousseaux, Sophie,Garcia-Fortanet, Jorge,Del Aguila Sanchez, Miguel Angel,Buchwald, Stephen L.
supporting information; experimental part, p. 9282 - 9285 (2011/08/04)
The palladium-catalyzed arylative dearomatization of phenols to yield spirocyclohexadienone products in good to excellent yields has been developed. Preliminary results demonstrate that the formation of the spirocyclic all-carbon quaternary center can be accomplished with high levels of enantiocontrol (up to 91% ee).