57137-55-0Relevant articles and documents
Photocatalytic CO2 Reduction Using Cu(I) Photosensitizers with a Fe(II) Catalyst
Takeda, Hiroyuki,Ohashi, Kenji,Sekine, Akiko,Ishitani, Osamu
supporting information, p. 4354 - 4357 (2016/05/09)
Photocatalytic systems developed from complexes with only abundant metals, i.e., CuI(dmp)(P)2+ (dmp =2,9-dimethyl-1,10-phenanthroline; P = phosphine ligand) as a redox photosensitizer and FeII(dmp)2(NCS)2 as a catalyst, produced CO as the main product by visible light irradiation. The best photocatalysis was obtained using a CuI complex with a tetradentate dmp ligand tethering two phosphine groups, where the turnover number and quantum yield of CO formation were 273 and 6.7%, respectively.
Migration insertion polymerization (MIP) of cyclopentadienyldicarbonyldiphenylphosphinopropyliron (FpP): A new concept for main chain metal-containing polymers (MCPs)
Wang, Xiaosong,Cao, Kai,Liu, Yibo,Tsang, Brian,Liew, Sean
supporting information, p. 3399 - 3402 (2013/04/10)
We report a conceptually new polymerization technique termed migration insertion polymerization (MIP) for main chain metal-containing polymer (MCP) synthesis. Cyclopentadienyldicarbonyldiphenylphosphinopropyliron (FpP) is synthesized and polymerized via M
Phosphinoalkylnitriles: Synthesis and coordination behaviour at palladium centres
Pitter, Stephan,Dinjus, Eckhard,Jung, Beate,Go?rls, Helmar
, p. 934 - 946 (2007/10/03)
Phosphinoalkylnitriles R2P-(CH2)n-CN {R = isopropyl (ipr), phenyl (ph), cyclohexyl (chex), n = 3, 6, 10} have been prepared starting from the corresponding secondary phosphines in an easy three step synthesis. All new compounds were characterized by their 1H-, 13C and 31P NMR data. Some of these new P, N ligands were used to prepare complexes [{R2P-(CH2)n-CN}2PdCl2] which were also identified by their NMR data. In addition the crystal structures of three derivatives, [{ipr2P-(CH2)3-CN} 2PdCl2] 7a, [{ph2P-(CH2)3-CN}2PdCl2] 7b and [{ph2P-(CH2)6-CN}2PdCl2] 8b were determined by X-ray analysis. The coordination mode of the phosphinoalkylnitriles in these complexes was found to be P-bonded resulting in a trans configuration. Palladium catalysts with 5a as ligund show high activies in the co-oligomerization of butadiene and carbon dioxide. The δ-lactone 11a is formed under very mild conditions.