56632-55-4

Basic information

• Product Name: cyclohexyl 2,3,4,6-tetra-O-benzyl-α-D-glucopyranoside
• Synonyms: cyclohexyl 2,3,4,6-tetra-O-benzyl-α-D-glucopyranoside
• CAS NO: 56632-55-4
• Molecular Weight: 622.802
• Mol File: 56632-55-4.mol
• Article Data: 72

Chemical Properties

• CAS DataBase Reference: cyclohexyl 2,3,4,6-tetra-O-benzyl-α-D-glucopyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: cyclohexyl 2,3,4,6-tetra-O-benzyl-α-D-glucopyranoside(56632-55-4)
• EPA Substance Registry System: cyclohexyl 2,3,4,6-tetra-O-benzyl-α-D-glucopyranoside(56632-55-4)

Safety Data

• Hazardous Substances Data: 56632-55-4(Hazardous Substances Data)

Upstream product

• 108-93-0 cyclohexanol 
• 13871-89-1 trimethylsilyl cyclohexyl ether 
• 78153-79-4 2,3,4,6-tetra-O-benzyl-β-D-glucopyranosyl fluoride 
• 89025-46-7 2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl fluoride 
• 89825-08-1 2,3,4,6-tetra-O-benzyl-1-O-trimethylsilyl-α,β-D-glucopyranose 
• 4196-35-4 2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl bromide 
• 6564-72-3 2,3,4,6-tetra-O-benzyl-D-glucopyranose 
• 4291-69-4 2,3,4,6-Tetra-O-benzyl-D-glucopyranose 
• 74808-09-6 2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl trichloroacetimidate 
• 129470-73-1 S-1-(1'-phenyl-1H-tetrazolyl) 2,3,4,6-tetra-O-benzyl-β-D-glucopyranose 
• 166733-02-4 S-(2,3,4,6-tetra-O-benzyl-β-D-glucopyranosyl)-N,N,N',N'-tetramethyl-N''-phenylphosphorodiamidimidothioate 
• 130854-82-9 C₄₄H₅₂N₃O₅PS 
• 96863-21-7 2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl dimethylphosphinothioate 
• 92414-02-3 2,3,4,6-tetra-O-benzyl-1-O-bromoacetyl-β-D-glucopyranose 

Relevant articles and documents

Metal-free glycosylation with glycosyl fluorides in liquid SO2

Liquid SO2 is a polar solvent that dissolves both covalent and ionic compounds. Sulfur dioxide possesses also Lewis acid properties, including the ability to covalently bind Lewis basic fluoride ions in a relatively stable fluorosulfite anion (FSO2?). Herein we report the application of liquid SO2 as a promoting solvent for glycosylation with glycosyl fluorides without any external additive. By using various temperature regimes, the method is applied for both armed and disarmed glucose and mannose-derived glycosyl fluorides in moderate to excellent yields. A series of pivaloyl-protected O- and S-mannosides, as well as one example of a C-mannoside, are synthesized to demonstrate the scope of the glycosyl acceptors. The formation of the fluorosulfite species during the glycosylation with glycosyl fluorides in liquid SO2 is proved by 19F NMR spectroscopy. A sulfur dioxide-assisted glycosylation mechanism that proceeds via solvent separated ion pairs is proposed, whereas the observed α,β-selectivity is substrate-controlled and depends on the thermodynamic equilibrium.

A visible light promoted O-glycosylation with glycosyl trichloroacetimidates using eosin Y as an organo photoacid

A photoacid catalyzed O-glycosylation of alcohols with glycosyl trichloroacetimidates in the presence of commercially available phenolic photoacids, fluorescein, 4′,5′-dibromo-fluorescein, and eosin Y under visible light irradiation by blue LEDs was devel

α-Selective glycosylations using glycosyl: N-(ortho-methoxyphenyl)trifluoroacetimidates

Six N-(o-methoxyphenyl)trifluoroacetimidate glycosyl donors have been synthesized and their role as glycosyl donors has been investigated. The donors were synthesized with complete -selectivity, except in one case, and were found to be stable. When Bi(OTf