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  • 55716-66-0 Structure
  • Basic information

    1. Product Name: 4-Aminobenzocyclobutene
    2. Synonyms: 4-Aminobenzocyclobutene;4-(cyclobut-1-en-1-yl)aniline;Bicyclo[4.2.0]octa-1,3,5,7-tetraen-3-aMine;4-AMBCB 4-Aminobenzocyclobutene;Bicyclo[4.2.0]octa-1,3,5-trien-3-amine
    3. CAS NO:55716-66-0
    4. Molecular Formula: C8H7N
    5. Molecular Weight: 117.15
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 55716-66-0.mol
    9. Article Data: 4
  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: 257.328°C at 760 mmHg
    3. Flash Point: 124.538°C
    4. Appearance: /
    5. Density: 1.156g/cm3
    6. Vapor Pressure: 0.015mmHg at 25°C
    7. Refractive Index: 1.66
    8. Storage Temp.: 2-8°C(protect from light)
    9. Solubility: N/A
    10. PKA: 5.17±0.20(Predicted)
    11. CAS DataBase Reference: 4-Aminobenzocyclobutene(CAS DataBase Reference)
    12. NIST Chemistry Reference: 4-Aminobenzocyclobutene(55716-66-0)
    13. EPA Substance Registry System: 4-Aminobenzocyclobutene(55716-66-0)
  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 55716-66-0(Hazardous Substances Data)

55716-66-0 Usage

Description

4-Aminobenzocyclobutene, with the molecular formula C10H11N, is a unique chemical compound derived from benzocyclobutene and characterized by the presence of an amino group. This rare and specialized compound holds promise in the realms of organic chemistry and material science due to its potential as a building block for synthesizing other organic compounds and its possible role in the creation of new materials with distinct properties and applications.

Uses

Used in Organic Chemistry:
4-Aminobenzocyclobutene is utilized as a key intermediate in the synthesis of various organic compounds, contributing to the development of novel chemical entities with specific functionalities and applications.
Used in Material Science:
In the field of material science, 4-Aminobenzocyclobutene is employed as a component in the design and fabrication of new materials. Its unique structure and properties allow it to contribute to the creation of materials with tailored characteristics for specialized applications.
Due to its specialized nature, 4-Aminobenzocyclobutene is not commonly found in mainstream chemical applications, indicating that its uses are currently limited to niche areas within the scientific community. However, ongoing research and development may uncover additional applications and expand its utility in the future.

Check Digit Verification of cas no

The CAS Registry Mumber 55716-66-0 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 5,5,7,1 and 6 respectively; the second part has 2 digits, 6 and 6 respectively.
Calculate Digit Verification of CAS Registry Number 55716-66:
(7*5)+(6*5)+(5*7)+(4*1)+(3*6)+(2*6)+(1*6)=140
140 % 10 = 0
So 55716-66-0 is a valid CAS Registry Number.
InChI:InChI=1/C8H9N/c9-8-4-3-6-1-2-7(6)5-8/h3-5H,1-2,9H2

55716-66-0SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 15, 2017

Revision Date: Aug 15, 2017

1.Identification

1.1 GHS Product identifier

Product name Bicyclo[4.2.0]octa-1,3,5,7-tetraen-3-amine

1.2 Other means of identification

Product number -
Other names bicyclo[4.2.0]octa-1(6),2,4-trien-4-amine

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:55716-66-0 SDS

55716-66-0Relevant articles and documents

Markgraf et al.

, p. 3261,3262 (1979)

COMPOUNDS AND METHODS FOR IDO AND TDO MODULATION, AND INDICATIONS THEREFOR

-

Paragraph 0367, (2019/10/15)

Disclosed are compounds of Formula (I) and (Ia) or a pharmaceutically acceptable salt, a solvate, a tautomer, a stereoisomer or a deuterated analog thereof, wherein R4, R5, R6, and R7 are as described in any of the embodiments described in this disclosure; compositions thereof; and uses thereof.

Relaxation processes in the excited state of C60-o-quinodimethane adducts

Nakamura, Yosuke,Minowa, Toshiyuki,Hayashida, Yoshitou,Tobita, Seiji,Shizuka, Haruo,Nishimura, Jan

, p. 377 - 382 (2007/10/03)

Intramolecular electron transfer and exciplex formation in a C60 adduct possessing an N,N-dimethylaniline (DMA) moiety, C60-DMA, in cyclohexane and benzonitrile have been investigated in comparison with the intermolecular reactions between C60-o-quinodimethane (OQD) and DMA. The fluorescence of C60-DMA in cyclohexane was little quenched by the DMA moiety and was almost the same as that of C60-OQD, in contrast with the decrease and red shift in the fluorescence of C60-OQD in the presence of excess DMA in cyclohexane, mainly resulting from exciplex formation. The difficulties in the intramolecular exciplex formation of C60-DMA in cyclohexane are considered to result from its unfavourable molecular structure, which also affects charge-transfer complex formation. On the other hand, in benzonitrile the fluorescence of C60-DMA was significantly quenched and red shifted. The quenching is due to the intramolecular electron transfer from the DMA moiety to the S1 state of the C60 moiety, where the rate constant was estimated as 1.5 × 1010 s-1. The red shift is brought about by the charge-transfer character in the S1 state, resulting from the through-bond interaction between the two chromophores. The transient absorption spectra of C60-DMA in cyclohexane exhibited the Tn ← T1 bands, in good agreement with those of C60-OQD without a dimethylamino group. In benzonitrile, however, the Tn ← T1 bands were considerably weakened by the decrease in the triplet population, and the lifetime (7 μs) of T1 was reduced relative to that in cyclohexane (28 μs). The decrease in the lifetime in benzonitrile can be ascribed to the weak charge-transfer interaction between the T1 of the C60 moiety and the S0 of the DMA moiety.

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