54417-83-3

Basic information

• Product Name: C₈H₁₀N^(1-)
• CAS NO: 54417-83-3
• Molecular Weight: 120.174
• Mol File: 54417-83-3.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: C₈H₁₀N^(1-)(CAS DataBase Reference)
• NIST Chemistry Reference: C₈H₁₀N^(1-)(54417-83-3)
• EPA Substance Registry System: C₈H₁₀N^(1-)(54417-83-3)

Safety Data

• Hazardous Substances Data: 54417-83-3(Hazardous Substances Data)

Upstream product

• 121-69-7 N,N-dimethyl-aniline 
• 100-04-9 p-dimethylaminobenzenediazonium chloride 
• 65738-85-4 p-Dimethylaminobenzendiazoradikal 

Relevant articles and documents

Effiziente Methode zur Erzeugung von Radikalanionen aus Benzolderivaten geringer Elektronenaffinitaet

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Pulse Radiolysis of Arenediazonium Salts in Water/tert.-Butanol

The pulse radiolysis of benzenediazonium tetrafluoroborate and its p-NMe2, p-MeO, p-Me, p-Cl, p-COOEt, and p-CN derivatives was studied in water/tert.-butanol mixtures.Absorption spectra observed at wavelengths between 400 and 700 nm were attributed to the recombination products (tetrazadienes) Ar-N=N-N=N-Ar of arenediazo radicals Ar-N=N. which are generated by a diffusion-controlled reaction of the solvated electrons with the solute.The recombination of Ar-N=N. competes with an unimolecular decay of these radicals.According to an inhomogeneous initial distribution of Ar-N=N. the apparent rate of the recombination reaction is higher than the diffusion-controlled limit.For the unimolecular decay of Ar-N=N. rate constants between (1.8 and 330) * 105s-1 were calculated.The tetrazadienes decompose unimolecularly with rate constants from (0.3 to 17) * 105s-1. - The rate constants of the decay of the arenediazo radicals as well as of the decomposition of tetrazadienes exhibit good Hammet plots with almost identical reaction constants indicating similar paths of nitrogen elimination.