54280-91-0

Basic information

• Product Name: 1-<(ethoxycarbonyl)methyl>-4-tert-butylcyclohexanol
• Synonyms: 1-<(ethoxycarbonyl)methyl>-4-tert-butylcyclohexanol
• CAS NO: 54280-91-0
• Molecular Weight: 242.359
• Mol File: 54280-91-0.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: 1-<(ethoxycarbonyl)methyl>-4-tert-butylcyclohexanol(CAS DataBase Reference)
• NIST Chemistry Reference: 1-<(ethoxycarbonyl)methyl>-4-tert-butylcyclohexanol(54280-91-0)
• EPA Substance Registry System: 1-<(ethoxycarbonyl)methyl>-4-tert-butylcyclohexanol(54280-91-0)

Safety Data

• Hazardous Substances Data: 54280-91-0(Hazardous Substances Data)

Upstream product

• 105-36-2 ethyl bromoacetate 
• 98-53-3 4-tercbutyl-cyclohexanone 
• 26954-26-7 ethyl lithioacetate 
• 5764-82-9 bromo(2-ethoxy-2-oxoethyl)zinc 

Downstream Products

• 129518-99-6 ethyl (4-tert-butylcyclohexylidene)acetate 
• 54281-01-5 1-<(ethoxycarbonyl)methyl>-4-tert-butylcyclohexene 
• 123992-62-1 ethyl (ξ-acetoxy-4β-tert-butyl-1-cyclohexyl)acetate 
• 41498-18-4 2-(4-(tert-butyl)cyclohexylidene)ethanol 
• 56300-88-0 2-(4-tert-butylcyclohexylidene)acetaldehyde 
• 123992-77-8 1-(diazoacetonylidene)-4-tert-butylcyclohexane 
• 28835-96-3 (4-tert-butylcyclohexylidene)acetic acid 
• 54281-02-6 2-(4-tert-butyl-cyclohex-1-enyl)-ethanol 

Relevant articles and documents

Metal chloride-promoted aldol reaction of α-dimethylsilylesters with aldehydes, ketones, and α-enones

In the presence of a catalytic amount of LiCl, α-dimethylsilylesters (α-DMS-esters) 1 smoothly reacted with various aldehydes at 30°C to give aldols in good to high yields. On the other hand, the aldol reaction with ketones was effectively promoted by MgCl2 rather than by LiCl. α-Enones also underwent the metal chloride-promoted addition of 1 at the carbonyl carbon or β-carbon. Georg Thieme Verlag Stuttgart.

Lithium Benzenetellurolate-induced Reformatsky-type Reaction in the Presence of Cerium Trichloride

Reformatsky-type reactions with PhTeLi in the presence of CeCl3 proceeded smoothly under mild conditions.The PhTeLi-CeCl3 reagent was particularly efficient for the reactions of sterically hindered and enolizable ketones; in the absence of CeCl3 unsatisfactory yields of the desired β-hydroxy ketone were obtained.It is assumed that CeCl3 reactions involve a cerium enolate intermediate.The stereoselectivity of the reaction between ethyl 2-bromopropionate and benzaldehyde is also described.