5294-56-4

Basic information

• Product Name: Propanedioic acid, (1-phenylethylidene)-, diethyl ester
• CAS NO: 5294-56-4
• Molecular Formula: C15H18O4
• Molecular Weight: 262.306
• Mol File: 5294-56-4.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: Propanedioic acid, (1-phenylethylidene)-, diethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Propanedioic acid, (1-phenylethylidene)-, diethyl ester(5294-56-4)
• EPA Substance Registry System: Propanedioic acid, (1-phenylethylidene)-, diethyl ester(5294-56-4)

Safety Data

• Hazardous Substances Data: 5294-56-4(Hazardous Substances Data)

Upstream product

• 932-87-6 1-Bromo-2-phenylacetylene 
• 105-53-3 diethyl malonate 
• 100-42-5 styrene 
• 996-82-7 sodium diethylmalonate 
• 181023-33-6 9-Methyl-9-phenyl-7,10-dithia-cyclohepta[de]naphthalene-8,8-dicarboxylic acid diethyl ester 
• 536-74-3 phenylacetylene 
• 98-86-2 acetophenone 
• 156462-92-9 2-phenylnaphtho<1,8-de><1,3>dithiin 
• 100-52-7 benzaldehyde 
• 181023-28-9 2-Methyl-2-phenyl-naphtho[1,8-de][1,3]dithiine 
• 570-08-1 diethyl acetylmalonate 
• 98-80-6 phenylboronic acid 

Downstream Products

• 19867-55-1 <α-Methyl-benzyliden>-malonsaeure 
• 14618-12-3 diethyl (1-phenylethyl)malonate 
• 106352-17-4 diethyl 3-bromo-2-phenylpropene-1,1-dicarboxylate 
• 226920-88-3 diethyl 3-cyano-2-phenylpropene-1,1-dicarboxylate 
• 226921-01-3 ethyl 5-cyano-1,2-dihydro-2-oxo-4-phenyl-6-trichloromethylpyridine-3-carboxylate 
• 226920-99-6 ethyl 1-benzoyl-5-cyano-1,2-dihydro-6-mercapto-2-oxo-4-phenyl-pyridine-3-carboxylate 
• 1134-71-0 ethyl (3R)-3-phenylbutanoate 
• 772-14-5 (R)-3-phenylbutyric acid 
• 150881-63-3 (3R)-2-(ethoxycarbonyl)-3-phenylbutanoic acid 

Relevant articles and documents

Asymmetric Hydrogenation of ?-Aryl Alkylidene Malonate Esters: Installing an Ester Group Significantly Increases the Efficiency

Herein, we report a practical method for efficient asymmetric hydrogenation of β-aryl alkylidene malonates. With a site-specifically tailored chiral spiro iridium catalyst, a series of β-aryl alkylidene malonate esters were hydrogenated to afford chiral m

Diethyl 2-aryl-3-cyanopropene-1,1-dicarboxylates: New versatile precursors in heterocyclic synthesis

An expeditious synthetic route for the title precursor is reported. It provides access to a variety of polyfunctionally substituted pyridines, pyridazines, pyrazolopyridines, thiophenes, and thienopyridines.

Specific Features of Reactions of Butyl- and Phenylacetylenes with CH-Acids

The reactions of butyl- and phenylacetylenes with cyanoacetic, malonic, and acetoacetic esters and acetylacetone in a polar solvent in the presence of mercuric acetate were studied. Intramolecular cyclization of unsaturated dicarbonyl compounds formed at