52358-73-3Relevant articles and documents
Halogen bonds of iodonium ions: A world dissimilar to silver coordination
Turunen, Lotta,Németh, Flóra Boróka,Decato, Daniel A.,Pápai, Imre,Berryman, Orion B.,Erdélyi, Máté
supporting information, p. 191 - 196 (2021/01/19)
A distinct difference between the three-center halogen bond and the analogous three-center coordinative bond of silver is demonstrated by computational, X-ray crystallographic and solution NMR spectroscopic investigations of their complexes with a bidentate Lewis base. Iodine(I) preferentially forms an entropically favored monomeric complex, whereas silver(I) forms enthalpically favored dimeric complexes. Counterion coordination considerably influences the structure of the silver complexes in the solution and solid state, whereas it does not have notable effect on the analogous halogen bond.
Bromination of naphthalene and derivatives: High temperature bromination XI
Dastan, Arif,Tahir, M. Nawaz,Uelkue, Dincer,Balci, Metin
, p. 12853 - 12864 (2007/10/03)
Thermal and photobromination of naphthalene and derivatives have been studied. Several hexabromo- (12, 13, 16 and 17), and tetrabromotetralin derivatives (23, 24, and 25) have been obtained as the major products, besides bromonaphthalene derivatives. Base-promoted elimination reactions of 12, 13, 16 and 17 provided di- (8) tri- (10) and tetrabromo-naphthalenes (22). A convenient method was developed for the synthesis of 1,3- dibromonaphthalene (26) starting from (24). The structures of these products were determined by 1H-,13C- NMR data and X-ray structural analysis.