49543-94-4

Basic information

• Product Name: Diethylsilanyl-phenyl-(1-phenyl-ethyl)-amine
• Synonyms: Diethylsilanyl-phenyl-(1-phenyl-ethyl)-amine
• CAS NO: 49543-94-4
• Molecular Weight: 283.489
• Mol File: 49543-94-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Diethylsilanyl-phenyl-(1-phenyl-ethyl)-amine(CAS DataBase Reference)
• NIST Chemistry Reference: Diethylsilanyl-phenyl-(1-phenyl-ethyl)-amine(49543-94-4)
• EPA Substance Registry System: Diethylsilanyl-phenyl-(1-phenyl-ethyl)-amine(49543-94-4)

Safety Data

• Hazardous Substances Data: 49543-94-4(Hazardous Substances Data)

Upstream product

• 542-91-6 H₂SiEt₂ 
• 1749-19-5 phenyl(1-phenylethylidene)amine 

Downstream Products

• 779-54-4 phenyl(1-phenylethyl)amine 

Relevant articles and documents

Hydrosilylation and Mukaiyama aldol-type reaction of quinolines and hydrosilylation of imines catalyzed by a mesoionic carbene-stabilized borenium ion

Aldimines and ketimines containing electron-donating and electron-withdrawing groups can be hydrosilylated with borenium catalysts at as low as 1 mol% catalyst loading at room temperature, providing the corresponding secondary amines in excellent yields. Reactions with 2-phenylquinoline gave the 1,4-hydrosilylquinoline product selectively which can be further functionalized in a one-pot synthesis to give unique γ-amino alcohol derivatives. Control experiments suggest that the borenium ion catalyzes both the hydrosilylation and subsequent addition to the aldehyde.