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484-17-3

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484-17-3 Usage

Description

9-PHENANTHROL, also known as a metabolite of Phenanthrene, is a phenanthrol that is phenanthrene in which a hydrogen attached to a carbon in the central ring has been replaced by a hydroxy group. It is characterized by its brown powder appearance and is used in various applications due to its unique chemical properties.

Uses

Used in Chemical Research:
9-PHENANTHROL is used as a research compound for investigating C K-edge and O K-edge near-edge X-ray absorption fine structure (NEXAFS) spectra of single-wall carbon nanotubes. This application helps in understanding the interactions and properties of these materials at a molecular level.
Used in Pharmaceutical Industry:
As a metabolite of Phenanthrene, 9-PHENANTHROL is used as a starting material or intermediate in the synthesis of various pharmaceutical compounds. Its unique chemical structure allows for the development of new drugs with potential therapeutic applications.
Used in Material Science:
9-PHENANTHROL, due to its brown powder form, can be used in the development of new materials or as an additive in the material science industry. Its specific properties may contribute to the enhancement of certain material characteristics, such as stability or reactivity.

Synthesis Reference(s)

The Journal of Organic Chemistry, 24, p. 86, 1959 DOI: 10.1021/jo01083a025Tetrahedron Letters, 29, p. 5459, 1988 DOI: 10.1016/S0040-4039(00)80786-8

Biochem/physiol Actions

9-Phenanthrol is inhibitor of the transient receptor potential melastatin 4 (TRPM) channel, a Ca2+ -activated non-selective cation channel.

Check Digit Verification of cas no

The CAS Registry Mumber 484-17-3 includes 6 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 3 digits, 4,8 and 4 respectively; the second part has 2 digits, 1 and 7 respectively.
Calculate Digit Verification of CAS Registry Number 484-17:
(5*4)+(4*8)+(3*4)+(2*1)+(1*7)=73
73 % 10 = 3
So 484-17-3 is a valid CAS Registry Number.
InChI:InChI=1/C14H10O/c15-14-9-10-5-1-2-6-11(10)12-7-3-4-8-13(12)14/h1-9,15H

484-17-3SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 20, 2017

Revision Date: Aug 20, 2017

1.Identification

1.1 GHS Product identifier

Product name 9-phenanthrol

1.2 Other means of identification

Product number -
Other names 9-Phenanthrol

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:484-17-3 SDS

484-17-3Relevant articles and documents

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Fieser,Jacobsen,Price

, p. 2163,2165 (1936)

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Itoh et al.

, p. 1059,1060-1062 (1979)

Preparation method of 9-hydroxyphenanthrene

-

, (2021/08/07)

The invention discloses a preparation method of 9-hydroxyphenanthrene, the preparation method comprises the following steps: taking a phenanthrene solution as a raw material, carrying out bromination, methoxylation and demethylation reaction to obtain the 9-hydroxyphenanthrene. The preparation method has the advantages of low preparation cost, high preparation efficiency, environmental friendliness, greatly improved product yield and high quality of the prepared product, is suitable for industrial production, and can be used for large-scale industrial preparation of 9-hydroxyphenanthrene and derivatives thereof.

β-Diketone boron difluoride dye-functionalized conjugated microporous polymers for efficient aerobic oxidative photocatalysis

Dong, Kaixun,Gong, Weitao,Hassan, Mehdi,Liu, Lu,Ning, Guiling

, p. 3905 - 3913 (2021/06/18)

Incorporation of organic chromophores into conjugated micro/mesoporous polymers (CMPs) provides a promising avenue for developing recyclable heterogeneous photocatalysts by overcoming tedious separation and low reusability of homogeneous organic dye-based photocatalysts. However, the design principle and the underlying structure-property relationship for fabricating and selecting various organic dye-embedded CMPs for efficient photocatalysis have not been well-constructed so far. In this study, we described the rational fabrication of two new CMPsviathe one-step Sonogashira coupling using β-diketone boron difluoride dye as the key linker and commonly used building blocks (triphenylamine/triphenylbenzene) as the cores. The resulting boron-dye containing CMPs were efficiently employed as the metal-free photocatalysts in two typical aerobic oxidative organic transformations including coupling of benzylamine and oxidation of aryl boronic acids to corresponding aryl phenols, which have never been explored with other boron-dye-embedded CMPs. They exhibited superior photocatalytic performance compared to their boron-free counterparts due to their wide visible-light absorption, narrow optical bandgaps, and extended π-conjugation due to boron-complexation. The present study establishes β-diketone boron difluoride dyes as efficient building blocks for fabricating new CMP-based photocatalysts.

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