45074-31-5Relevant articles and documents
AGENT FOR DYEING HAIR, CONTAINING AT LEAST ONE ORGANIC SILICON COMPOUND, A COLORING COMPOUND AND A FILM-FORMING, HYDROPHILIC POLYMER
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, (2021/11/26)
The subject of the present disclosure is a composition for coloring keratinous material, in particular human hair, containing in a cosmetic carrier (a) at least one organic silicon compound selected from silanes having one, two or three silicon atoms, said organic silicon compound further comprising one or more basic chemical functions and one or more hydroxyl groups or hydrolysable groups per molecule,(b) at least one colorant compound from the group of pigments and/or direct dyes, and(c) at least one film-forming hydrophilic polymer.
Tuning cooperativity by controlling the linker length of silica-supported amines in catalysis and CO2 capture
Brunelli, Nicholas A.,Didas, Stephanie A.,Venkatasubbaiah, Krishnan,Jones, Christopher W.
supporting information, p. 13950 - 13953 (2012/10/29)
Cooperative interactions between aminoalkylsilanes and silanols on a silica surface can be controlled by varying the length of the alkyl linker attaching the amine to the silica surface from C1 (methyl) to C5 (pentyl). The linker length strongly affects the catalytic cooperativity of amines and silanols in aldol condensations as well as the adsorptive cooperativity for CO2 capture. The catalytic cooperativity increases with the linker length up to propyl (C3), with longer, more flexible linkers (up to C5) providing no additional benefit or hindrance. Short linkers (C1 and C2) limit the beneficial amine-silanol cooperativity in aldol condensations, resulting in lower catalytic rates than with the C3+ linkers. For the same materials, the adsorptive cooperativity exhibits similar trends for CO2 capture efficiency.
Azido-silane compositions
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, (2008/06/13)
Azido-containing silane compositions of matter useful as coupling agents in the production of polymer composite articles.