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  • 4-Isopropenylphenol CAS 4286-23-1 Factory 4-(1-Methylvinyl)phenol PRICE IN STOCK 4-(prop-1-en-2-yl)phenol COA p-Isopropenylphenol CAS 4286-23-1

    Cas No: 4286-23-1

  • USD $ 3.5-5.0 / Kiloliter

  • 5 Kiloliter

  • 3000 Metric Ton/Month

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  • 4286-23-1 Structure
  • Basic information

    1. Product Name: 4-Isopropenylphenol
    2. Synonyms: 4-Isopropenylphenol;4-(1-Methylvinyl)phenol;4-Hydroxy α-methylstyrene;4-Hydroxy-α-methylstyrene;α-Methyl-4-hydroxystyrene;p-Isopropenylphenol;Phenol, 4-(1-methylethenyl)-;4-isoprophenylphenol
    3. CAS NO:4286-23-1
    4. Molecular Formula: C9H10O
    5. Molecular Weight: 134.18
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 4286-23-1.mol
    9. Article Data: 25
  • Chemical Properties

    1. Melting Point: 85℃
    2. Boiling Point: 136-137℃ (20 Torr)
    3. Flash Point: 97.7±8.4℃
    4. Appearance: /
    5. Density: 1.003±0.06 g/cm3 (20 ºC 760 Torr)
    6. Vapor Pressure: 0.0875mmHg at 25°C
    7. Refractive Index: 1.546
    8. Storage Temp.: 2-8°C
    9. Solubility: Chloroform (Slightly), DMSO (Slightly), Ethyl Acetate (Slightly)
    10. PKA: 9.80±0.15(Predicted)
    11. Stability: Light Sensitive, Temperature Sensitive
    12. CAS DataBase Reference: 4-Isopropenylphenol(CAS DataBase Reference)
    13. NIST Chemistry Reference: 4-Isopropenylphenol(4286-23-1)
    14. EPA Substance Registry System: 4-Isopropenylphenol(4286-23-1)
  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: IRRITANT
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 4286-23-1(Hazardous Substances Data)

4286-23-1 Usage

Uses

4-Isopropenylphenol is an intermediate in the synthesis of 3,5-Dichlorobisphenol A (D433555), a monomer used for policarbonate and epoxy resins; exhibits estrogenic activity.

Check Digit Verification of cas no

The CAS Registry Mumber 4286-23-1 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 4,2,8 and 6 respectively; the second part has 2 digits, 2 and 3 respectively.
Calculate Digit Verification of CAS Registry Number 4286-23:
(6*4)+(5*2)+(4*8)+(3*6)+(2*2)+(1*3)=91
91 % 10 = 1
So 4286-23-1 is a valid CAS Registry Number.
InChI:InChI=1/C9H10O/c1-7(2)8-3-5-9(10)6-4-8/h3-6,10H,1H2,2H3

4286-23-1SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 17, 2017

Revision Date: Aug 17, 2017

1.Identification

1.1 GHS Product identifier

Product name 4-(Prop-1-en-2-yl)phenol

1.2 Other means of identification

Product number -
Other names 4-Isopropenylphenol

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:4286-23-1 SDS

4286-23-1Synthetic route

4-isopropenylphenol
4286-23-1

4-isopropenylphenol

Conditions
ConditionsYield
With sodium hydroxide at 230 - 250℃; under 15 Torr; Pyrolysis;90%
With potassium superoxide; 18-crown-6 ether In N,N-dimethyl-formamide at 25℃; for 35h;30%
With sodium hydroxide (heating);
With sodium hydroxide at 230 - 250℃; Pyrolysis;
1-isopropenyl-4-methoxybenzene
1712-69-2

1-isopropenyl-4-methoxybenzene

4-isopropenylphenol
4286-23-1

4-isopropenylphenol

Conditions
ConditionsYield
With sodium thioethylate In N,N-dimethyl-formamide for 0.5h; Heating;89%
Methyltriphenylphosphonium bromide
1779-49-3

Methyltriphenylphosphonium bromide

4-Hydroxyacetophenone
99-93-4

4-Hydroxyacetophenone

4-isopropenylphenol
4286-23-1

4-isopropenylphenol

Conditions
ConditionsYield
Stage #1: Methyltriphenylphosphonium bromide With sodium hexamethyldisilazane In tetrahydrofuran at 20℃; for 1.5h; Cooling;
Stage #2: 4-Hydroxyacetophenone In tetrahydrofuran for 4h;
14%
Stage #1: Methyltriphenylphosphonium bromide With potassium tert-butylate In tetrahydrofuran at 0℃; for 0.75h;
Stage #2: 4-Hydroxyacetophenone In tetrahydrofuran at 20℃; for 18h;
Stage #1: Methyltriphenylphosphonium bromide With potassium tert-butylate In tetrahydrofuran at 0℃; for 1h; Inert atmosphere;
Stage #2: 4-Hydroxyacetophenone In tetrahydrofuran at 20℃; for 6h; Inert atmosphere;
4-Isopropylphenol
99-89-8

4-Isopropylphenol

4-isopropenylphenol
4286-23-1

4-isopropenylphenol

Conditions
ConditionsYield
With chromium corundum at 600℃;

A

4-isopropenylphenol
4286-23-1

4-isopropenylphenol

B

phenol
108-95-2

phenol

Conditions
ConditionsYield
at 200 - 280℃; Yield given;
With sulfuric acid In water at 250℃; for 0.5h; pH=2.0; Kinetics; Further Variations:; Reagents; pH-values; Temperatures;
With [Fe(IV)(O)(N-benzyl-N,N',N'-tris(2-pyridylmethyl)-1,2-diaminoethane)](2+) In water; acetonitrile at 24.84℃;
1,1,3,3-tetramethyl-2,3-dihydro-1H-isoindol-2-yloxoyl radical
80037-90-7

1,1,3,3-tetramethyl-2,3-dihydro-1H-isoindol-2-yloxoyl radical

isopropenylbenzene
98-83-9

isopropenylbenzene

A

4-isopropenylphenol
4286-23-1

4-isopropenylphenol

B

2-phenyl-3-(1,1,3,3-tetramethylisoindolin-2-yloxy)prop-1-ene
93066-52-5

2-phenyl-3-(1,1,3,3-tetramethylisoindolin-2-yloxy)prop-1-ene

C

2-phenyl-1-(1,1,3,3-tetramethylisoindolin-2-yloxy)propan-2-ol
97141-97-4

2-phenyl-1-(1,1,3,3-tetramethylisoindolin-2-yloxy)propan-2-ol

D

2-phenyl-2-(1,1,3,3-tetramethylisoindolin-2-yloxy)propan-1-ol
97141-93-0

2-phenyl-2-(1,1,3,3-tetramethylisoindolin-2-yloxy)propan-1-ol

Conditions
ConditionsYield
With 2-(t-butylazo)prop-2-yl hydroperoxide at 60℃; for 6h; Rate constant; Product distribution; investigation of the reaction of hydroxyl radicals with polymerizable olefins by radical trapping technique; rate constants in competition experiments with cyclohexane;
With 2-(t-butylazo)prop-2-yl hydroperoxide at 60℃; for 6h; in sealed vessel;A 9 % Turnov.
B 5 % Turnov.
C 3 % Turnov.
D 83 % Turnov.
isopropenylbenzene
98-83-9

isopropenylbenzene

4-isopropenylphenol
4286-23-1

4-isopropenylphenol

Conditions
ConditionsYield
With phosphate buffer; air; 1,4-dihydronicotinamide adenine dinucleotide at 45℃; methane mono-oxygenase from Methylococcus capsulatus (Bath); Yield given;
4-Isopropyliden-2,5-cyclohexadienon
55182-48-4

4-Isopropyliden-2,5-cyclohexadienon

4-isopropenylphenol
4286-23-1

4-isopropenylphenol

Conditions
ConditionsYield
With acetic acid; triethylamine In chloroform
Fuller's earth

Fuller's earth

A

4-isopropenylphenol
4286-23-1

4-isopropenylphenol

B

phenol
108-95-2

phenol

Conditions
ConditionsYield
at 200 - 230℃;
3-<4-hydroxy-phenyl>-glutaconic acid

3-<4-hydroxy-phenyl>-glutaconic acid

A

4-isopropenylphenol
4286-23-1

4-isopropenylphenol

B

p-hydroxy-3-methyl-trans-cinnamic acid
149636-52-2

p-hydroxy-3-methyl-trans-cinnamic acid

Conditions
ConditionsYield
With water at 150℃;
cis-sphagnum acid
50670-02-5, 57100-28-4

cis-sphagnum acid

water
7732-18-5

water

A

4-isopropenylphenol
4286-23-1

4-isopropenylphenol

B

p-hydroxy-3-methyl-trans-cinnamic acid
149636-52-2

p-hydroxy-3-methyl-trans-cinnamic acid

Conditions
ConditionsYield
at 150℃;
3-<4-hydroxy-phenyl>-pentene-(2c?)-dioic acid

3-<4-hydroxy-phenyl>-pentene-(2c?)-dioic acid

A

4-isopropenylphenol
4286-23-1

4-isopropenylphenol

B

p-hydroxy-3-methyl-trans-cinnamic acid
149636-52-2

p-hydroxy-3-methyl-trans-cinnamic acid

Conditions
ConditionsYield
With water at 150℃;
4-Hydroxyacetophenone
99-93-4

4-Hydroxyacetophenone

pinacolboratamethylenetriphenylphosphonium iodide

pinacolboratamethylenetriphenylphosphonium iodide

4-isopropenylphenol
4286-23-1

4-isopropenylphenol

Conditions
ConditionsYield
Stage #1: pinacolboratamethylenetriphenylphosphonium iodide With lithium hexamethyldisilazane In N,N,N,N,N,N-hexamethylphosphoric triamide at 0℃; for 2h;
Stage #2: 4-Hydroxyacetophenone In N,N,N,N,N,N-hexamethylphosphoric triamide at -78 - 20℃;
83 % Chromat.
C9H11O(1+)*HO4S(1-)

C9H11O(1+)*HO4S(1-)

4-isopropenylphenol
4286-23-1

4-isopropenylphenol

Conditions
ConditionsYield
Stage #1: C9H11O(1+)*HO4S(1-) With water cooling;
Stage #2: With sodium hydroxide Heating;
1-(4-methoxyphenyl)ethanone
100-06-1

1-(4-methoxyphenyl)ethanone

4-isopropenylphenol
4286-23-1

4-isopropenylphenol

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: 92 percent / n-BuLi / diethyl ether; hexane / 12 h / Ambient temperature
2: 89 percent / EtSNa / dimethylformamide / 0.5 h / Heating
View Scheme
polycarbonate resin

polycarbonate resin

cyclohexanol
108-93-0

cyclohexanol

A

BPA
80-05-7

BPA

B

para-tert-butylphenol
98-54-4

para-tert-butylphenol

C

4-isopropenylphenol
4286-23-1

4-isopropenylphenol

D

dicyclohexyl carbonate
4427-97-8

dicyclohexyl carbonate

E

cyclohexanone
108-94-1

cyclohexanone

F

cyclohexene
110-83-8

cyclohexene

G

phenol
108-95-2

phenol

Conditions
ConditionsYield
sodium carbonate at 200℃; under 37503.8 Torr; for 1h; Product distribution / selectivity; liquid phase pyrolysis oilized reaction;A 19.95 %Chromat.
B 1.07 %Chromat.
C 0.74 %Chromat.
D 18.19 %Chromat.
E 1.6 %Chromat.
F 0.19 %Chromat.
G 0.46 %Chromat.
phenol
108-95-2

phenol

4-isopropenylphenol
4286-23-1

4-isopropenylphenol

Conditions
ConditionsYield
In acetone
In acetone
2-[1-(4-hydroxyphenyl)-1-methylethyl]-phenol
837-08-1

2-[1-(4-hydroxyphenyl)-1-methylethyl]-phenol

A

4-isopropenylphenol
4286-23-1

4-isopropenylphenol

B

phenol
108-95-2

phenol

Conditions
ConditionsYield
sodium hydroxide at 190℃; under 120 Torr; Product distribution / selectivity;

A

4-isopropenylphenol
4286-23-1

4-isopropenylphenol

B

C9H8O3

C9H8O3

C

C9H8O3

C9H8O3

D

C15H14O4

C15H14O4

E

4-[1-(4-hydroxyphenyl)-1-methyl-ethyl]-benzene-1,2-diol
79371-66-7

4-[1-(4-hydroxyphenyl)-1-methyl-ethyl]-benzene-1,2-diol

Conditions
ConditionsYield
With nitrogen doped K2Nb4O11 In water for 6h; Photolysis;

4286-23-1Relevant articles and documents

Preparation of nitrogen doped K2Nb4O11 with high photocatalytic activity for degradation of organic pollutants

Qiu, Yongfu,Wang, Lei,Leung, Chi-Fai,Liu, Guijian,Yang, Shihe,Lau, Tai-Chu

, p. 23 - 30 (2011)

Nitrogen doped K2Nb4O11 (K 2Nb4O11-N) has been prepared by solid state reaction between K2Nb4O11 and urea at 400 °C. K2Nb4O11-N has been characterized by XRD, SEM, XPS and UV/vis diffuse reflectance. The photodegradation of various organic pollutants in water by this material, including Orange G (OG), bisphenol A (BPA) and pentachlorophenol (PCP) have been studied at λ > 330 nm and >399 nm. The results show that the photocatalytic activity of K 2Nb4O11-N at >399 nm is higher than those of K2Nb4O11 and Degussa TiO2 P25, indicating the activating effect of nitrogen doping. A mechanism for the photodegradation of organic substrates by K2Nb4O 11-N is proposed.

Oxidative degradation of toxic organic pollutants by water soluble nonheme iron(iv)-oxo complexes of polydentate nitrogen donor ligands

Jana, Rahul Dev,Munshi, Sandip,Paine, Tapan Kanti

, p. 5590 - 5597 (2021/05/04)

The ability of four mononuclear nonheme iron(iv)-oxo complexes supported by polydentate nitrogen donor ligands to degrade organic pollutants has been investigated. The water soluble iron(ii) complexes upon treatment with ceric ammonium nitrate (CAN) in aqueous solution are converted into the corresponding iron(iv)-oxo complexes. The hydrogen atom transfer (HAT) ability of iron(iv)-oxo species has been exploited for the oxidation of halogenated phenols and other toxic pollutants with weak X-H (X = C, O, S,etc.) bonds. The iron-oxo oxidants can oxidize chloro- and fluorophenols with moderate to high yields under stoichiometric as well as catalytic conditions. Furthermore, these oxidants perform selective oxidative degradation of several persistent organic pollutants (POPs) such as bisphenol A, nonylphenol, 2,4-D (2,4-dichlorophenoxyacetic acid) and gammaxene. This work demonstrates the utility of water soluble iron(iv)-oxo complexes as potential catalysts for the oxidative degradation of a wide range of toxic pollutants, and these oxidants could be considered as an alternative to conventional oxidation methods.

Degradation of bisphenol A and acute toxicity reduction by different thermo-tolerant ascomycete strains isolated from arid soils

Mtibaà, Rim,Olicón-Hernández, Dario Rafael,Pozo, Clementina,Nasri, Moncef,Mechichi, Tahar,González, Jesus,Aranda, Elisabet

, p. 87 - 96 (2018/03/21)

Four different laccase-producing strains were isolated from arid soils and used for bisphenol A (BPA) degradation. These strains were identified as Chaetomium strumarium G5I, Thielavia arenaria CH9, Thielavia arenaria HJ22 and Thielavia arenaria SM1(III) by internal transcribed spacer 5.8 S rDNA analysis. Residual BPA was evaluated by HPLC analysis during 48 h of incubation. A complete removal of BPA was observed by the whole cell fungal cultures within different times, depending on each strain. C. strumarium G5I was the most efficient degrader, showing 100% of removal within 8 h of incubation. The degradation of BPA was accompanied by the production of laccase and dye decolorizing peroxidase (DyP) under degradation conditions. The presence of aminobenzotriazole (ABT) as an inhibitor of cytochrome P450s monooxygenases (CYP) demonstrated a slight decrease in BPA removal rate, suggesting the effective contribution of CYP in the conversion. The great involvement of laccase in BPA transformation together with cell-associated enzymes, such as CYP, was supported by the identification of hydroxylated metabolites by ultra-high performance liquid chromatography-mass spectroscopy (UHPLC-MS). The metabolic pathway of BPA transformation was proposed based on the detected metabolites. The acute toxicity of BPA and its products was investigated and showed a significant reduction, except for T. arenaria SM1(III) that did not caused reduction of toxicity (IC50 8%), possibly due to the presence of toxic metabolites. The results of the present study point out the potential application of the isolated ascomycetes in pollutant removal processes, especially C. strumarium G5I as an efficient degrader of BPA.

Novel synthesis of Ag decorated TiO2 anchored on zeolites derived from coal fly ash for the photodegradation of bisphenol-A

Hlekelele, Lerato,Franklyn, Paul J.,Dziike, Farai,Durbach, Shane H.

supporting information, p. 1902 - 1912 (2018/02/09)

The disposal of millions of tons of coal fly ash (CFA) threatens the environment, hence means to reuse CFA are highly sought after. In this study, CFA was reused to make materials which were tested for water purification. Zeolitic material (CFA-Zeo) was derived from CFA by a 2-step alkali-fusion hydrothermal method and then composited with TiO2 nanoparticles using a novel resin-gel technique. CFA-Zeo loadings were 15 and 30 wt% in the resulting TiO2/CFA-Zeo composites. These composites were then loaded with 1 wt% Ag nanoparticles by a deposition-precipitation technique using NaOH and urea. CFA-Zeo rods (morphology confirmed by TEM) were confirmed by PXRD to be sodium aluminum silicate hydrate. TEM analyses of the CFA-Zeo rods in the composites revealed them to be completely coated with TiO2 nanoparticles that had Ag nanoparticles on their surfaces. The photoluminescence emission peak of TiO2 was found to be significantly higher than that of TiO2/CFA-Zeo composites, with the TiO2/CFA-Zeo composites that were loaded with Ag having even lower emission intensities. UV-vis DRS spectra showed that CFA-Zeo had no effect on the band gap of TiO2, while composites that contained Ag had a wide absorption band in the visible region. The photocatalytic efficiency of these materials was then determined using bisphenol-A (BPA) as a model compound under both UV and visible light. Except for the 30 wt% TiO2/CFA-Zeo composites without Ag, all of the composites had superior photoactivity to uncomposited TiO2 under both UV and visible light. On the other hand, composites with Ag nanoparticles showed the best photoactivities. The superior photoactivities of these composites under UV-light were mainly attributed to the separation of charge carriers, whereas under visible light it was attributed to the ability of silver to harvest visible light through surface plasmon resonance (SPR).

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