42817-44-7

Basic information

• Product Name: 2-Propen-1-amine, N,N-dimethyl-3-phenyl-, (E)-
• Synonyms: E-3-phenyl-N,N-dimethyl-2-propenamine;Dimethyl-trans-cinnamyl-amin;dimethyl-trans-cinnamyl-amine;DIMETHYLAMINOMETHYLSTYRENE
• CAS NO: 42817-44-7
• Molecular Formula: C11H15N
• Molecular Weight: 161.247
• Mol File: 42817-44-7.mol
• Article Data: 18

Chemical Properties

• Boiling Point: 62 °C(Press: 0.7 Torr)
• Density: 0.944±0.06 g/cm3(Predicted)
• CAS DataBase Reference: 2-Propen-1-amine, N,N-dimethyl-3-phenyl-, (E)-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Propen-1-amine, N,N-dimethyl-3-phenyl-, (E)-(42817-44-7)
• EPA Substance Registry System: 2-Propen-1-amine, N,N-dimethyl-3-phenyl-, (E)-(42817-44-7)

Safety Data

• Hazardous Substances Data: 42817-44-7(Hazardous Substances Data)

Upstream product

• 14371-10-9 (E)-3-phenylpropenal 
• 68-12-2 N,N-dimethyl-formamide 
• 4407-36-7 (2E)-3-phenyl-2-propen-1-ol 
• 2568-65-2 N,N-dimethyl-3-phenyl-2-propyn-1-amine 
• 79750-53-1 (E)-3-(4-nitrophenyl)prop-2-en-1-yl bromide 
• 124-40-3 dimethyl amine 
• 35271-56-8 (E)-4-nitrocinnamyl alcohol 
• 555-16-8 4-nitrobenzaldehdye 
• 24393-61-1 ethyl (E)-3-(4-nitrophenyl)-2-propenoate 
• 14674-28-3 N-benzylidene-2-methylbenzenesulfonamide 
• 205582-30-5 [(dimethylamino)ethyl]triphenylphosphonium bromide 
• 102-92-1 Cinnamoyl chloride 
• 2757-10-0 (E)-N-methyl-3-phenyl-acrylamide 
• 140-10-3 (E)-3-phenylacrylic acid 

Downstream Products

• 50876-69-2 cinnamyldimethyl-<(2E)-2-methylpenta-2,4-dienyl>ammonium bromide 
• 50876-70-5 cinnamyldimethyl-<(2E)-4-methylpenta-2,4-dienyl>ammonium bromide 
• 14371-10-9 (E)-3-phenylpropenal 
• 75712-94-6 (Z)-N,N-dimethyl-3-phenylprop-2-en-1-amine 
• 73687-55-5 (E)-N,N-Dimethyl-3-phenyl-1-propen-1-amine 
• 1581720-49-1 C₂₀H₂₄N₂O 
• 1581720-07-1 (2S,3S)-N-benzyl-2-(dimethylamino)-3-phenylpent-4-enamide 
• 1581720-10-6 (2S,3S)-2-(dimethylamino)-N-methoxy-N-methyl-3-phenylpent-4-enamide 
• 1581720-12-8 (2S,3S)-2-(dimethylamino)-3-phenyl-1-(pyrrolidin-1-yl)pent-4-en-1-one 
• 1581720-14-0 (2S,3S)-methyl 2-(dimethylamino)-3-phenylpent-4-enoate 
• 1581720-16-2 (2S,3S)-2-(dimethylamino)-3-phenylpent-4-en-1-ol 

Relevant articles and documents

Method for preparing tertiary amine organic compound from photocatalytically decomposing substituted formamide

The invention discloses a method for preparing a tertiary amine compound from aldehyde and substituted formamide under the action of a photocatalyst. The method is characterized in that the reaction can be performed only by illumination under the conditions of no hydrogen and no reducing agent. The method is suitable for various aldehydes including aromatic aldehydes, fatty aldehydes and the like,has the characteristics of few byproducts and high product yield, does not need to use hydrogen in the reaction, avoids the use of noble metal hydrogenation catalysts, and has obvious technical and economic effects and application prospects.

Synthesis of tertiary amines by direct Br?nsted acid catalyzed reductive amination

Tertiary amines are ubiquitous and valuable compounds in synthetic chemistry, with a wide range of applications in organocatalysis, organometallic complexes, biological processes and pharmaceutical chemistry. One of the most frequently used pathways to synthesize tertiary amines is the reductive amination reaction of carbonyl compounds. Despite developments of numerous new reductive amination methods in the past few decades, this reaction generally requires non-atom-economic processes with harsh conditions and toxic transition-metal catalysts. Herein, we report simple yet practical protocols using triflic acid as a catalyst to efficiently promote the direct reductive amination reactions of carbonyl compounds on a broad range of substrates. Applications of this new method to generate valuable heterocyclic frameworks and polyamines are also included.

Cobalt-catalyzed (Z)-selective semihydrogenation of alkynes with molecular hydrogen

Cobalt-catalyzed highly (Z)-selective semihydrogenation of alkynes using molecular H2 was developed using commercially available and cheap cobalt precursors. A variety of (Z)-alkenes were obtained in moderate to excellent selectivities [(Z)-alkene/(E)-alkene/alkane ratio up to >99 : 1 : 1] and it was found that the readily available ethylenediamine ligand is crucial in determining the selectivity.