41320-28-9

Basic information

• Product Name: S-cyclohexyl S-methyl dithiocarbonate
• Synonyms: S-cyclohexyl S-methyl dithiocarbonate
• CAS NO: 41320-28-9
• Molecular Weight: 190.331
• Mol File: 41320-28-9.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: S-cyclohexyl S-methyl dithiocarbonate(CAS DataBase Reference)
• NIST Chemistry Reference: S-cyclohexyl S-methyl dithiocarbonate(41320-28-9)
• EPA Substance Registry System: S-cyclohexyl S-methyl dithiocarbonate(41320-28-9)

Safety Data

• Hazardous Substances Data: 41320-28-9(Hazardous Substances Data)

Upstream product

• 41320-40-5 <<(methylthio)thiocarbonyl>oxy>cyclohexane 

Relevant articles and documents

Catalytic thione-thiol rearrangement of xanthates by 4- dialkylaminopyridine

Pyridines bearing electron-donating substituents are useful catalysts for the rearrangement of O,S-dialkyl xanthates (1) to S,S-dialkyl dithiocarbonates (2). The rearrangement was analyzed by semiempirical and ab initio molecular orbital methods. The transition-structure analyses indicate that the pyridine-ring nitrogen of dialkylaminopyridine rather than the dialkylamino nitrogen attacks the O-alkyl carbon of xanthates. The reaction proceeds through an S(N)2 mechanism to give the dithiolcarbonate anion (RSCOS-) which acts as an actual catalyst.

4-PIPERIDINOPYRIDINE AS AN EFFECTIVE CATALYST FOR THIONE-THIOL REARRANGEMENT OF XANTHATES

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Catalytic rearrangement of O,S-Dialkyl dithiocarbonates to S,S-Dialkyl dithiocarbonates. IV. Use of boron trifluoride etherate as catalyst

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