39887-27-9

Basic information

• Product Name: N-allyl-4-bromobenzamide
• Synonyms: N-allyl-4-bromobenzamide;UKRORGSYN-BB BBV-069231;N-allyl-4-bromobenzamide(SALTDATA: FREE)
• CAS NO: 39887-27-9
• Molecular Formula: C₁₀H₁₀BrNO
• Molecular Weight: 240.1
• Mol File: 39887-27-9.mol
• Article Data: 10

Chemical Properties

• Boiling Point: 354.6°C at 760 mmHg
• Flash Point: 168.3°C
• Appearance: /
• Density: 1.379g/cm³
• Vapor Pressure: 3.31E-05mmHg at 25°C
• Refractive Index: 1.563
• CAS DataBase Reference: N-allyl-4-bromobenzamide(CAS DataBase Reference)
• NIST Chemistry Reference: N-allyl-4-bromobenzamide(39887-27-9)
• EPA Substance Registry System: N-allyl-4-bromobenzamide(39887-27-9)

Safety Data

• Hazardous Substances Data: 39887-27-9(Hazardous Substances Data)

Usage

InChI:InChI=1/C10H10BrNO/c1-2-7-12-10(13)8-3-5-9(11)6-4-8/h2-6H,1,7H2,(H,12,13)

Upstream product

• 107-11-9 1-amino-2-propene 
• 586-75-4 4-chlorobenzoyl chloride 
• 586-76-5 4-Bromobenzoic acid 
• 1122-91-4 4-bromo-benzaldehyde 
• 1340546-31-7 diisopropyl 1-(4-bromobenzoyl)hydrazine-1,2-dicarboxylate 
• 589-87-7 1,4-bromoiodobenzene 
• 13939-06-5 molybdenum hexacarbonyl 

Downstream Products

• 39887-73-5 N-Allyl-4-brombenzimidylchlorid 
• 1395225-02-1 5-(bromomethyl)-2-(4-bromophenyl)oxazole 
• 1415585-59-9 (E)-4-bromo-N-(4,4,4-trifluorobut-2-en-1-yl)benzamide 
• 1085698-16-3 4-(allylcarbamoyl)benzoic acid 
• 1433416-62-6 (2-(4-bromophenyl)-4,5-dihydrooxazol-5-yl)methyl acetate 
• 180422-59-7 N-allyl-4-formylbenzamide 

Relevant articles and documents

Sequential catalytic carbonylation reactions for sustainable synthesis of biologically relevant entities

The sustainable synthesis of highly functionalised formylcarboxamide compounds with biological relevance is reported through a sequential aminocarbonylation/hydroformylation approach. The optimisation of palladium-catalysed aminocarbonylation of iodoaromatic substrates, using allylamine as nucleophile was first performed, with molybdenum hexacarbonyl as alternative CO source versus gaseous carbon monoxide. The combination of microwave irradiation with molybdenum hexacarbonyl allowed to selectively prepare a set of N-heterocyclic-based allylcarboxamides. Subsequent rhodium-catalysed hydroformylation of the allylcarboxamide intermediates led to the preparation of new pyridine, pyrazoline and chalcone derivatives containing both carboxamide and formyl moieties.

Preparation of Heterocycles via Visible-Light-Driven Aerobic Selenation of Olefins with Diselenides

The aerobic dehydrogenative cyclization of alkenes with easily accessible diselenides facilitated by visible light is reported. Notably, the features of this transition-metal-free protocol are pronounced efficiency and practicality, good functional group

Electrochemical Fluorocyclization of N-Allylcarboxamides to 2-Oxazolines by Hypervalent Iodine Mediator

A resource saving protocol for the synthesis of 5-fluoromethyl-2-oxazolines by using electrochemistry has been realized. Thereby, a hypervalent iodine species I(III) is generated by anodic oxidation in the presence of Et3N·5HF and mediates the