37680-26-5

Basic information

• Product Name: Bicyclo[4.2.0]oct-6-ene
• CAS NO: 37680-26-5
• Molecular Formula: C8H12
• Molecular Weight: 108.183
• Mol File: 37680-26-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Bicyclo[4.2.0]oct-6-ene(CAS DataBase Reference)
• NIST Chemistry Reference: Bicyclo[4.2.0]oct-6-ene(37680-26-5)
• EPA Substance Registry System: Bicyclo[4.2.0]oct-6-ene(37680-26-5)

Safety Data

• Hazardous Substances Data: 37680-26-5(Hazardous Substances Data)

Upstream product

• 73733-09-2 bicyclo<5.1.0>octan-2-one tosylhydrazone 

Relevant articles and documents

EFFECT OF THE STRUCTURE OF BICYCLIC CARBENES ON THE DIRECTION OF THEIR STABILIZATION

By pyrolysis of the sodium salts of bicyclooctan-2-one and bicyclononan-2-one tosylhydrazones the corresponding carbenes were generated.The first of them undergoes fragmentation with the formation of 1-octen-7-yne and rearrangement to bicyclooct-6-ene, and the second rearranges to bicyclodec-8-ene and forms the products from transannular insertion, i.e., tricyclo2,4>decane and tricyclo2,4>decane.The difference in the direction of stabilization in these carbenes is due to the geometry of the arrangement of the three-membered ring in relation to the vacant p orbital.