376367-93-0

Basic information

• Product Name: Firpic
• Synonyms: Firpic;Bis(4,6-difluorophenylpyridinato-N,C2)picolinatoiridium;bis[3,5-difluoro-2-(2-pyridinyl-kn)phenyl-kc](2-pyridinecarboxylato-kn1,ko2)-iridium;Bis(4,6-difluorophenylpyridine)( picolinate) iridiuM(Ⅲ);FIrPic , Firpic Produkt Beschreibung;IridiuM(III) bis[(4,6-difluorophenyl)-pyridinato-N,C2']picolate;iridiuM(III)bis[2-(4',6'-difluorophenyl)pyridinato-N,C(2')]-picolinate;FPicIr
• CAS NO: 376367-93-0
• Molecular Formula: C28H16F4IrN3O2
• Molecular Weight: 694.665
• Product Categories: olde Materials;oled materials;fine chemicals, specialty chemicals, intermediates, electronic chemical, organic synthesis, functional materials
• Mol File: 376367-93-0.mol
• Article Data: 7

Chemical Properties

• Melting Point: 330-335°C
• Appearance: /
• Storage Temp.: Sealed in dry,Room Temperature
• CAS DataBase Reference: Firpic(CAS DataBase Reference)
• NIST Chemistry Reference: Firpic(376367-93-0)
• EPA Substance Registry System: Firpic(376367-93-0)

Safety Data

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26
• WGK Germany: 3
• Hazardous Substances Data: 376367-93-0(Hazardous Substances Data)

Usage

Description

Firpic, also known as Bis[2-(4,6-difluorophenyl)pyridinato-C2,N](picolinato)iridium, is a light blue heteroleptic triplet emitter and a bis-cyclometallated iridium complex. It is widely investigated for its attractive sky-blue emission, high emission efficiency, and suitable energy levels as a phosphorescent dopant material.

Uses

Used in Organic Light Emitting Diodes (OLEDs):
Firpic is used as a phosphorescent dopant material for its attractive sky-blue emission, high emission efficiency, and suitable energy levels. It is typically doped into host matrices such as tetra-aryl silanes and short conjugation length carbazole derivatives, showing a good quantum efficiency.
Used in Suzuki Reaction:
Firpic is also utilized in the Suzuki reaction, a widely used method in organic chemistry for the formation of carbon-carbon bonds, particularly in the synthesis of various organic compounds and materials.

Classification

Iridium complex, Phosphorescent blue emitter, Organic light-emitting diodes, Organic electronics.

Upstream product

• 57665-05-1 sodium picolinate 
• 98-98-6 2-Picolinic acid 
• 391604-55-0 2-(2,4-difluorophenyl)pyridine 

Downstream Products

• 98-98-6 2-Picolinic acid 

Relevant articles and documents

Molecular-engineered [Ir(Fppy)2(Mepic)] towards efficient blue-emission

A novel Ir(III) complex, [Ir(Fppy)2(Mepic)] (Fppy = 2-(2,4-difluorophenyl)pyridinate; Mepic = 3-methylpyridine-2-carboxylate) was engineered to show a blue phosphorescence with an impressive unitary quantum yield in our search for luminescent metal complexes for low cost displays and efficient lighting devices. Application of the Golden rule through Franck-Condon spectral analyses along with TD-DFT calculations and comparisons to the [Ir(Fppy)2(pic)] complex have provided insights on the mixing extension between charge-transfer (CT) and ligand-centered (LC) excited states in the emissive lowest-energy triplet transition for different media. The relatively narrow and vibronically-structured emission of [Ir(Fppy)2(Mepic)] at 298 K mainly arises from a spin-orbit-induced mixed 3MLCT-LCIr(Fppy)→Fppy/3LLCTFppy→Mepic excited state, with an enhanced MLCT character because of the methyl addition to pic. In frozen media at 77 K, the CT contribution is extinguished, leading to a pure LCFppy emission, with a similar emissive spectral profile to the free ligand, FppyH. The efficient blue emission shows that the complex is suitable for high-performance light-emitting devices and for thermo- and rigidity-sensors.

Inter-ligand energy transfer and related emission change in the cyclometalated heteroleptic iridium complex: Facile and efficient color tuning over the whole visible range by the ancillary ligand structure

We report a novel color tuning methodology in the electrophosphorescent iridium complex by substituting one cyclometalating ligand to an ancillary ligand as an emitting center. Highly efficient exothermic inter-ligand energy transfer (ILET) from the MLCT

Synthetic method of organometallic iridium compound

A synthetic method for preparing organometallic iridium compounds is provided and includes the two steps of (1) synthesizing a di-iridium compound with a halogenated bridge: L2Ir(μ?X)2IrL2, L; and (2) reacting L2Ir(μ?X)2IrL2 with a ligand to give the product [C?]N]2Ir (LX). The invention is an improvement over the traditional method for preparing such compounds and has the advantages of shortened reaction time, increased yield, and products of over 99% purity obtained without chromatography.