35666-13-8

Basic information

• Product Name: Benzoic acid, 4-bromo-, 4-nitrophenyl ester
• CAS NO: 35666-13-8
• Molecular Formula: C13H8BrNO4
• Molecular Weight: 322.115
• Mol File: 35666-13-8.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: Benzoic acid, 4-bromo-, 4-nitrophenyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Benzoic acid, 4-bromo-, 4-nitrophenyl ester(35666-13-8)
• EPA Substance Registry System: Benzoic acid, 4-bromo-, 4-nitrophenyl ester(35666-13-8)

Safety Data

• Hazardous Substances Data: 35666-13-8(Hazardous Substances Data)

Upstream product

• 100-02-7 4-nitro-phenol 
• 586-76-5 4-Bromobenzoic acid 
• 586-75-4 4-chlorobenzoyl chloride 
• 1122-91-4 4-bromo-benzaldehyde 

Downstream Products

• 33696-03-6 4-chlorophenyl 4-bromobenzoate 
• 97839-40-2 4-Brom-thiobenzoesaeure-S-phenylester 
• 1192840-81-5 C₁₈H₁₈Br₂N₂O₂S₂ 
• 4714-24-3 1-bromo-4-styrylbenzene 
• 1179348-62-9 1-(4-bromophenyl)-2-(2-dimethyl(oxo)-λ⁶-sulfanylidene)ethan-1-one 

Relevant articles and documents

Amidation and esterification of carboxylic acids with amines and phenols by N,N′-diisopropylcarbodiimide: A new approach for amide and ester bond formation in water

The present study reports the successful synthesis of two important and abundant functional groups “ester and amide” by N,N′-diisopropylcarbodiimide (DIC) in water as a green solvent. A wide range of substrates could be employed with high functional group tolerance. The products were obtained in high yields after short reaction times. This method provides an efficient, economic, simple and very mild protocol for ester and amide bond formation in aqueous media. In addition, this work not only may lead to environmentally benign systems but also will provide a new aspect of organic chemistry in water.

Palladium/NHC-catalyzed oxidative esterification of aldehydes with phenols

A palladium-catalyzed oxidative esterification of aldehydes with phenols is described, using air as the clean oxidant. This reaction tolerates many functional groups, providing esters with yields ranging from moderate to excellent.

Kinetics of the reaction of 4-nitrophenyl benzoates with 4-chlorophenol in the presence of potassium carbonate in dimethylformamide

The effect of the substituent in the benzoyl group on the relative rate and activation parameters of transesterification of substituted 4-nitrophenyl benzoates with 4-chlorophenol in dimethylformamide in the presence of potassium carbonate was studied by the competing reaction technique. The whole series of benzoates showed the enthalpy-entropy compensation effect. 4-Nitrophenyl benzoates having electronacceptor substituents give rise to isokinetic relationship with an isokinetic temperature β of 382 K. The mechanism of the transesterification process is discussed. Pleiades Publishing, Inc., 2006.