350693-36-6

Basic information

• Product Name: Silane, [3,3-diphenyl-3-[(trimethylsilyl)oxy]-1-propynyl]trimethyl-
• CAS NO: 350693-36-6
• Molecular Formula: C21H28OSi2
• Molecular Weight: 352.624
• Mol File: 350693-36-6.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: Silane, [3,3-diphenyl-3-[(trimethylsilyl)oxy]-1-propynyl]trimethyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Silane, [3,3-diphenyl-3-[(trimethylsilyl)oxy]-1-propynyl]trimethyl-(350693-36-6)
• EPA Substance Registry System: Silane, [3,3-diphenyl-3-[(trimethylsilyl)oxy]-1-propynyl]trimethyl-(350693-36-6)

Safety Data

• Hazardous Substances Data: 350693-36-6(Hazardous Substances Data)

Upstream product

• 75-77-4 chloro-trimethyl-silane 
• 73502-43-9 1,1-diphenyl-3-(trimethylsilyl)prop-2-yn-1-ol 
• 16029-98-4 trimethylsilyl iodide 
• 121284-44-4 O-(trimethylsilyl)-1,1-diphenyl-2-propyn-1-ol 
• 3923-52-2 1,1-diphenyl-2-propyn-1-ol 

Downstream Products

• 1095216-71-9 3-phenyl-3-(trimethylsilyl)-2,3-dihydroinden-1-one 
• 1095216-69-5 1,1,4,4-tetraphenyl-3,6-bis(trimethylsilyl)hex-1,2-dien-5-yne 

Relevant articles and documents

NEW (TRIORGANOSILYL)ALKYNES AND THEIR DERIVATIVES AND A NEW CATALYTIC METHOD FOR OBTAINING NEW AND CONVENTIONAL SUBSTITUTED (TRIORGANOSILYL)ALKYNES AND THEIR DERIVATIVES

The present invention relates to new (triorganosilyl)alkynes and their derivatives having general formula 1 R1—C≡C—Z (I) In its second aspect, this invention relates to a new selective method for the preparation of new and conventional (triorga

Silylative coupling of terminal alkynes with iodosilanes: New catalytic activation of sp-hybridized carbon-hydrogen bonds

The [{Ir(μ-Cl)(CO)2}2] (I)-catalyzed reaction of terminal alkynes and diynes with Me3SiI with the aid of NEt(i-Pr)2 occurs smoothly, leading to the formation of mono- and bis-silyl-functionalized alkynyl derivat

Novel carbon-carbon bond-forming reactions using carbocations produced from substituted propargyl silyl ethers by the action of TMSOTf

Highly useful carbon-carbon bond forming reactions using stable allenyl, propargyl, or allyl-propargyl hybrid cations have been developed. These carbocations could be generated from silyl 1-(π-donor)-substituted propargyl ethers by the action of trimethylsilyl trifluoromethanesulfonate in dichloromethane at -78 °C to room temperature and could be attacked nucleophilically by electron rich arenes, allylsilanes, or enol silyl ethers, giving rise to allenes, alkynes, and their derivatives. A novel method for regio- and stereoselective synthesis of conjugated enynes utilizing allyl-propargyl hybrid cations has also been established.