34993-51-6 Usage
Description
(R)-3-Phenylcyclohexanone, with the CAS number 34993-51-6, is a chemical compound resulting from a single-step reaction between 2-Cyclohexen-1-one (CAS number 930-68-7) and Potassium Phenyltrifluoroborate (CAS number 153766-81-5). It is an essential building block in the synthesis of various organic compounds and has unique properties that make it valuable in different applications.
Uses
Used in Chiral Porous Organic Frameworks (POFs) Industry:
(R)-3-Phenylcyclohexanone is used as a key component in the preparation of chiral porous organic frameworks (POFs) for asymmetric heterogeneous catalysis. Its presence in the POFs contributes to the selective adsorption and separation of chiral molecules, which is crucial in the production of enantiomerically pure compounds, essential in pharmaceuticals and agrochemicals.
Used in Gas Chromatography Industry:
(R)-3-Phenylcyclohexanone is also utilized in the field of gas chromatography for the separation of complex mixtures. Its unique chemical properties allow for the efficient and accurate separation of various components in a mixture, making it a valuable tool in analytical chemistry and quality control processes.
Check Digit Verification of cas no
The CAS Registry Mumber 34993-51-6 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 3,4,9,9 and 3 respectively; the second part has 2 digits, 5 and 1 respectively.
Calculate Digit Verification of CAS Registry Number 34993-51:
(7*3)+(6*4)+(5*9)+(4*9)+(3*3)+(2*5)+(1*1)=146
146 % 10 = 6
So 34993-51-6 is a valid CAS Registry Number.
InChI:InChI=1/C12H14O/c13-12-8-4-7-11(9-12)10-5-2-1-3-6-10/h1-3,5-6,11H,4,7-9H2/t11-/m1/s1
34993-51-6Relevant articles and documents
Enantioselective Hydrogenation of Endocyclic Enones: the Solution to a Historical Problem?
Lang, Qiwei,Yang, Huaxin,Gu, Guoxian,Feng, Qiang,Wen, Jialin,Zhang, Xumu
, p. 933 - 936 (2021/03/03)
The enantioselective hydrogenation of endocyclic enones has been a historical problem for homogeneous catalysis. We herein report an efficient method to reduce endocyclic enones with molecular hydrogen. Catalyzed by a rhodium/Zhaophos complex, a variety of enones with five-, six- or seven-member ring were hydrogenated with high enantioselectivity (92%—99% ee). Excellent chemo- and enantioselectivity demonstrated this method was successfully applied in the enantioselective hydrogenation of citral to produce enantio-enriched citronellal.
C1-Symmetric Binap Derivative Featuring Single Diferrocenylphosphino-Donor Moiety
Enomoto, Yuuki,Ichiryu, Hiroki,Hu, Hao,Ura, Yasuyuki,Ogasawara, Masamichi
supporting information, p. 1020 - 1024 (2021/05/07)
A C1-symmetric chiral bisphosphine, FcPh-Binap (1), which possesses a single diferrocenylphosphino moiety together with a conventional Ph2P-substituent, was prepared in enantiomerically pure forms. Ligand 1 is sterically less demanding than Fc-Segphos (A)
Enantioselective Conjugate Addition of Stabilized Arylzinc Iodide to Enones: an Improved Protocol of the Hayashi Reaction
Casotti, Gianluca,Rositano, Vincenzo,Iuliano, Anna
, p. 1126 - 1131 (2020/12/17)
Stabilised arylzinc iodide, prepared by direct insertion of zinc into aryl iodides, were used as nucleophiles in the Hayashi Rh-catalysed enantioselective conjugate addition to enones. The reaction conditions were optimized in the addition of phenylzinc i
