34896-80-5

Basic information

• Product Name: 3-BROMOPHENYLMETHYLSULFONE
• Synonyms: 3-BROMOPHENYLMETHYLSULFONE;3-Bromo phenyl methyl;1-Bromo-3-methanesulfonyl-benzene;3-BROMO PHENYL METHYL SULFONE 98%MIN;1-bromo-3-(methylsulfonyl)benzene;3-Bromophenylmethylsulfone ,98%;3-BROMOPHENYLMETHYLS;3-Bromophenyl methyl sulphone
• CAS NO: 34896-80-5
• Molecular Formula: C₇H₇BrO₂S
• Molecular Weight: 235.1
• EINECS: 1312995-182-4
• Product Categories: Miscellaneous;Aromatics Compounds;Aromatics;Sulfur & Selenium Compounds
• Mol File: 34896-80-5.mol
• Article Data: 39

Chemical Properties

• Melting Point: 100-104°C
• Boiling Point: 362.8 °C at 760 mmHg
• Flash Point: 173.2 °C
• Appearance: /
• Density: 1.595g/cm³
• Vapor Pressure: 3.93E-05mmHg at 25°C
• Refractive Index: 1.563
• Storage Temp.: -20°C Freezer
• Solubility: Chloroform
• CAS DataBase Reference: 3-BROMOPHENYLMETHYLSULFONE(CAS DataBase Reference)
• NIST Chemistry Reference: 3-BROMOPHENYLMETHYLSULFONE(34896-80-5)
• EPA Substance Registry System: 3-BROMOPHENYLMETHYLSULFONE(34896-80-5)

Safety Data

• Safety Statements: 24/25
• Hazardous Substances Data: 34896-80-5(Hazardous Substances Data)

Usage

Chemical Properties

White Solid

InChI:InChI=1/C7H7BrO2S/c1-11(9,10)7-4-2-3-6(8)5-7/h2-5H,1H3

Upstream product

• 33733-73-2 3-bromo-1-(methylthio)benzene 
• 512-56-1 trimethyl phosphite 
• 591-18-4 1-Bromo-3-iodobenzene 
• 20277-69-4 sodium methansulfinate 
• 3996-51-8 m-bromophenylosulfinylacetic acid 
• 3996-39-2 [(3-bromophenyl)sulfanyl]acetic acid 
• 108-36-1 1,3-dibromobenzene 
• 6320-01-0 3-Bromothiophenol 
• 29959-92-0 1-bromo-3-methanesulfinyl-benzene 
• 89598-96-9 (3-bromophenyl)boronic acid 
• 77-78-1 dimethyl sulfate 

Downstream Products

• 178482-89-8 3-(3-Methanesulfonyl-phenyl)-2,3-dihydro-pyrrole-1-carboxylic acid methyl ester 
• 474710-18-4 1-[3-(methylsulfonyl)phenyl]-1,4-diazepan 
• 346684-50-2 cis-4-(3-methanesulfonyl-phenyl)-2,6-dimethyl-1-propyl-piperazine 
• 107623-36-9 1-methanesulfonyl-3-[(4-nitrobenzene)sulfonyl]benzene 
• 686351-11-1 1-[(1-allylbut-3-enyl)sulfonyl]-3-bromobenzene 
• 1520073-12-4 3-bromophenyl 3-buten-1-yl sulfone 
• 686351-15-5 (1R)-2-{[6-({4-[3-(3-cyclopenten-1-ylsulfonyl)phenyl]butyl}oxy)hexyl]amino}-1-(2,2-dimethyl-4H-1,3-benzodioxin-6-yl)ethanol 
• 686351-14-4 (5R)-3-[6-({4-[3-(3-cyclopenten-1-ylsulfonyl)phenyl]butyl}oxy)hexyl]-5-(2,2-dimethyl-4H-1,3-benzodioxin-6-yl)-1,3-oxazolidin-2-one 
• 686351-13-3 (5R)-5-(2,2-dimethyl-4H-1,3-benzodioxin-6-yl)-3-(6-{[4-(3-{[1-(2-propen-1-yl)-3-buten-1-yl]sulfonyl}phenyl)butyl]oxy}hexyl)-1,3-oxazolidin-2-one 
• 156907-84-5 [3H]-(-)-OSU 6162 hydrochloride 
• 160866-61-5 PNU 180222 
• 504398-38-3 C₁₂H₁₇NO₂S*C₄H₆O₆ 
• 160866-61-5 3-(3-methanesulfonylphenyl)piperidine 
• 160777-44-6 3-(3-Methanesulfonyl-phenyl)-pyridine; hydrochloride 

Relevant articles and documents

Flow Electrosynthesis of Sulfoxides, Sulfones, and Sulfoximines without Supporting Electrolytes

An efficient electrochemical flow process for the selective oxidation of sulfides to sulfoxides and sulfones and of sulfoxides toN-cyanosulfoximines has been developed. In total, 69 examples of sulfoxides, sulfones, andN-cyanosulfoximines have been synthesized in good to excellent yields and with high current efficiencies. The synthesis was assisted and facilitated through a supporting electrolyte-free, fully automated electrochemical protocol that highlights the advantages of flow electrolysis.

A {Ti6W4}-Cluster-Substituted Polyoxotungstate: Synthesis, Structure, and Catalytic Oxidation Properties

A novel Ti-W-O-cluster-substituted tungstoantimonate (TA), [H2N(CH3)2]3Na4H9[{Ti6W4O18(OH)(H2O)3}(B-α-SbW9O33)3]·20H2O (1), has been made by hydrothermal reactions of trivacant [B-α-SbW9O33]9- units, Ti4+ cations, and WO42- anions in the presence of [H2N(CH3)2]·Cl and structurally characterized. Intriguingly, the polyoxoanion of 1 is constructed from three [B-α-SbW9O33]9- units and a previously unobserved decanuclear heterometallic Ti-W-O cluster [Ti6W4O18(OH)(H2O)3]11+ ({Ti6W4}) that is comprised of an octahedral [Ti6WO6(H2O)3]18+ cluster and an edge-sharing [W3O12(OH)]7- fragment via six W-O-Ti/W linkers. Furthermore, studies on the catalytic oxidation properties reveal that 1 possesses good catalytic activity toward the oxidation reactions of various sulfides and cyclooctene based on the environmentally friendly oxidant H2O2.

Three Zr(IV)-Substituted Polyoxotungstate Aggregates: Structural Transformation from Tungstoantimonate to Tungstophosphate Induced by pH

Three novel Zr-substituted polyoxotungstate aggregates [H2N(CH3)2]7NaH2[Zr2Sb2O3(A-α-PW9O34)2]·16H2O (1), [H2N(CH3)2]6H12[ZrSb4(OH)O2(A-α-PW8O32)(A-α-PW9O34)]2·33H2O (2), and [H2N(CH3)2]4Na11.5H4.5[Zr4W8Sb4P5O49(OH)5(B-α-SbW9O33)2]·53H2O (3) have been made in hydrothermal reactions of the [B-α-SbW9O33]9- precursor with Zr4+ cations and PO43- anions in the presence of dimethylamine hydrochloride and sodium acetate buffer (pH = 4.8) and structurally characterized. Different pH values induce structural transformation from tungstoantimonate (TA) to tungstophosphate (TP). 1 is a di-Zr-substituted sandwich-type TP, the tetranuclear heterometallic [Zr2Sb2O3]8+ entity sandwiched by two [A-α-PW9O34]9- moieties. 2 is a double sandwich-type structure, which can be perceived as two equivalent sandwiched [Sb3(PW8O32)(PW9O34)]11- further sandwiching one [Sb2Zr2(OH)2O4]4+ core to form a novel large-size sandwich-type architecture. Different from 1 and 2, 3 is a tetra-Zr-substituted sandwiched configuration, in which two [B-α-SbW9O33]9- fragments sandwich a unique 21-core Sb-P-W-Zr oxo cluster ({Zr4W8Sb4P5}). Furthermore, the catalytic oxidation of aromatic thioethers by 3 as the heterogeneous catalyst has been investigated, showing high conversion and remarkable selectivity as well as excellent recyclability.