33732-68-2

Basic information

• Product Name: 1-Chloro-4-phenylbicyclo[2.2.2]octane
• Synonyms: 1-Chloro-4-phenylbicyclo[2.2.2]octane
• CAS NO: 33732-68-2
• Molecular Formula: C₁₄H₁₇Cl
• Molecular Weight: 220.7378
• Mol File: 33732-68-2.mol
• Article Data: 1

Chemical Properties

• Boiling Point: 313.2°Cat760mmHg
• Flash Point: 132.3°C
• Appearance: /
• Density: 1.12g/cm³
• Vapor Pressure: 0.00093mmHg at 25°C
• Refractive Index: 1.571
• CAS DataBase Reference: 1-Chloro-4-phenylbicyclo[2.2.2]octane(CAS DataBase Reference)
• NIST Chemistry Reference: 1-Chloro-4-phenylbicyclo[2.2.2]octane(33732-68-2)
• EPA Substance Registry System: 1-Chloro-4-phenylbicyclo[2.2.2]octane(33732-68-2)

Safety Data

• Hazardous Substances Data: 33732-68-2(Hazardous Substances Data)

Usage

Type of Compound

Bicyclic organic compound

Contains

Chloro group and phenyl group

Usage

a. Organic synthesis substrate for various reactions
b. Grignard reactions
c. Ring-opening reactions
d. Chiral auxiliary in asymmetric synthesis
e. Starting material for pharmaceuticals and other organic compounds

Physical State

Colorless liquid at room temperature

Applications

a. Research
b. Industrial applications
c. Pharmaceutical industry
d. Agrochemical industry
e. Production of fine chemicals

InChI:InChI=1/C14H17Cl/c15-14-9-6-13(7-10-14,8-11-14)12-4-2-1-3-5-12/h1-5H,6-11H2

Upstream product

• 2001-62-9 4-Phenylbicyclo<2.2.2>octan-1-ol 
• 6555-88-0 1-methoxy-4-phenylbicyclo[2.2.2]octane 
• 3850-62-2 4-Methoxy-1-phenyl-bicyclo<2.2.2>-octan-2-on 

Downstream Products

• 23062-63-7 1,4-Diphenyl-bicyclo<2.2.2>octane 
• 33732-72-8 1,4-bis-(4-cyanophenyl)bicyclo[2.2.2]octane 
• 33732-71-7 1,4-bis(4-bromophenyl)bicyclo<2.2.2>octane 
• 33732-70-6 1,4-Bis(4'-nitrophenyl)bicyclo<2.2.2>octane 

Relevant articles and documents

SYNTHESIS OF BRIDGEHEAD CHLORO-, BROMO- AND IODOBICYCLOOCTANES

The paper describes transformations of hydroxy-, acetoxy- or methoxy-bridgehead bicyclooctanes into bridgehead chloro, bromo or iodo derivatives by action of inorganic halides in the medium of orthophosphoric or polyphosphoric acids.