327628-40-0

Basic information

• Product Name: [(E)-γ-(dimethylphenylsilyl)allyl]diisopinocamphenylborane
• Synonyms: [(E)-γ-(dimethylphenylsilyl)allyl]diisopinocamphenylborane
• CAS NO: 327628-40-0
• Molecular Weight: 460.627
• Mol File: 327628-40-0.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: [(E)-γ-(dimethylphenylsilyl)allyl]diisopinocamphenylborane(CAS DataBase Reference)
• NIST Chemistry Reference: [(E)-γ-(dimethylphenylsilyl)allyl]diisopinocamphenylborane(327628-40-0)
• EPA Substance Registry System: [(E)-γ-(dimethylphenylsilyl)allyl]diisopinocamphenylborane(327628-40-0)

Safety Data

• Hazardous Substances Data: 327628-40-0(Hazardous Substances Data)

Upstream product

• 18001-18-8 allyldimethylphenylsilane 
• 85134-98-1 (-)-B-methoxydiisopinocampheylborane 

Downstream Products

• 538334-76-8 (1R,2S,3R,4S,5S,6R)-5,6-dibenzyloxy-4-(tert-butyldimethylsilyloxy)-3-(dimethylphenylsilanyl)cyclohexane-1,2-diol 
• 538334-77-9 (1S,2R,3R,4S,5S,6R)-5,6-dibenzyloxy-4-(tert-butyldimethylsilyloxy)-3-(dimethylphenylsilanyl)cyclohexane-1,2-diol 
• 538334-73-5 (2R,3S,4R,5R)-4,5-dibenzyloxy-3-(tert-butyldimethylsilyloxy)-2-(dimethylphenylsilanyl)cyclohexene 
• 538334-65-5 (1S,2S,3S,4R,5S,6R)-5,6-dibenzyloxy-3-(dimethylphenylsilanyl)cyclohexane-1,2,4-triol 
• 538334-74-6 (1R,2S,3R,4S,5S,6R)-5,6-dibenzyloxy-3-(dimethylphenylsilanyl)cyclohexane-1,2,4-triol 
• 538334-70-2 (1R,2S,5R,6R)-5,6-dibenzyloxy-2-(dimethylphenylsilanyl)cyclohex-3-enol 
• 538334-72-4 (1S,2R,5R,6R)-5,6-dibenzyloxy-2-(dimethylphenylsilanyl)cyclohex-3-enol 
• 863604-34-6 (3S,4R,15R,19R)-4,15-bis(tert-bytyldimethylsilanyloxy)-19-(tert-butyldiphenylsilanyloxy)-3-(dimethylphenylsilanyl)eicos-1-en-17-yne 
• 863604-37-9 (3S,4R)-3-(dimethylphenylsilanyl)-4-(tert-butyldimethylsilanyloxy)tridec-1-ene 
• 863604-53-9 (3S,4R,15R,19R)-15-(tert-butyldimethylsilanyloxy)-19-(tert-butyldiphenylsilanyloxy)-3-(dimethylphenylsilanyl)eicos-1-en-17-yn-4-ol 
• 867357-72-0 (2R,2'S,4'S,5R,5'R)-4'-(dimethylphenylsilanyl)-5-[(1R)-1-(tert-butyldimethylsilanyloxy)undecyl]-5'-[(1S)-1-(tert-butyldimethylsilanyloxy)undecyl]octahydro-2,2'-bifuran 
• 863604-36-8 (3S,4R)-3-(dimethylphenylsilanyl)-4-hydroxytridec-1-ene 
• 867357-63-9 (2R,5S)-5-(benzyloxymethyl)-2-[(1R)-1-(hydroxy)undecyl]tetrahydrofuran 
• 538334-67-7 (3S,4R,5S,6R)-5,6-dibenzyloxy-3-(dimethylphenylsilanyl)octa-1,7-dien-4-ol 

Relevant articles and documents

[3 + 2]-Annulation reactions of chiral allylsilanes and chiral aldehydes. Studies on the synthesis of bis-tetrahydrofuran substructures of annonaceous acetogenins

Double asymmetric [3 + 2]-annulation reactions of chiral β-silyloxylallylsilanes with chiral 2-tetrahydrofuranyl carboxaldehydes have been studied, leading to the stereocontrolled synthesis of six diastereomeric bis-tetrahydrofuran structures correspondin