32750-01-9 Usage
Description
[1,1-Biphenyl]-2,2-diol,6,6-dimethyl-(9CI), also known as 2,2'-dimethyl-1,1'-biphenyl-2,2'-diol, is a chemical compound with the molecular formula C14H14O2. It features a biphenyl structure with two hydroxyl groups at the 2,2' positions and two methyl groups at the 6, 6' positions. This organic compound is commonly utilized as a building block in the synthesis of various organic compounds and pharmaceuticals, making it valuable in the fields of chemistry and medicinal chemistry. However, due to its potential health hazards and toxicity, it is crucial to handle this compound with care.
Uses
Used in Organic Synthesis:
[1,1-Biphenyl]-2,2-diol,6,6-dimethyl-(9CI) is used as a building block in the synthesis of various organic compounds. Its unique structure allows for the creation of a wide range of molecules with diverse properties and applications.
Used in Pharmaceutical Synthesis:
In the pharmaceutical industry, [1,1-Biphenyl]-2,2-diol,6,6-dimethyl-(9CI) is used as a key intermediate in the development of new drugs. Its presence in the molecular structure can influence the pharmacological properties of the final product, contributing to the discovery of novel therapeutic agents.
Used in Chemical Research:
[1,1-Biphenyl]-2,2-diol,6,6-dimethyl-(9CI) is also employed in chemical research to study the properties and reactions of biphenyl-based compounds. This helps in understanding the fundamental aspects of organic chemistry and can lead to the development of new synthetic methods and applications.
Check Digit Verification of cas no
The CAS Registry Mumber 32750-01-9 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 3,2,7,5 and 0 respectively; the second part has 2 digits, 0 and 1 respectively.
Calculate Digit Verification of CAS Registry Number 32750-01:
(7*3)+(6*2)+(5*7)+(4*5)+(3*0)+(2*0)+(1*1)=89
89 % 10 = 9
So 32750-01-9 is a valid CAS Registry Number.
32750-01-9Relevant articles and documents
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Adams,Baker
, p. 535 (1941)
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Hexafluoroisopropanol-Enabled Copper-Catalyzed Asymmetric Halogenation of Cyclic Diaryliodoniums for the Synthesis of Axially Chiral 2,2′-Dihalobiaryls
Ke, Jie,Zu, Bing,Guo, Yonghong,Li, Yingzi,He, Chuan
, p. 329 - 333 (2021/01/13)
An efficient asymmetric halogenation of cyclic diaryliodonium salts is demonstrated, which gives access to a wide range of axially chiral 2,2′-dihalobiaryls in good to excellent yields and with excellent enantioselectivities. The use of CuX with chiral bisoxazoline ligand and tetrabutylammonium halides in the unique solvent of hexafluoroisopropanol (HFIP) led to the best results in the process. The axially chiral 2,2′-dihalobiaryls can be transformed into a number of enantiopure chiral ligands that could be potentially useful in asymmetric catalysis.
Macromolecular helicity induction and memory in a poly(biphenylylacetylene) bearing an ester group and its application to a chiral stationary phase for high-performance liquid chromatography
Ishidate, Ryoma,Shimomura, Kouhei,Ikai, Tomoyuki,Kanoh, Shigeyoshi,Maeda, Katsuhiro
, p. 946 - 948 (2015/08/24)
An optically inactive poly(biphenylylacetylene) bearing an ester group at the 4′-position of the pendants formed a preferred-handed helical conformation and biased axial chirality in the pendants through a noncovalent interaction with a chiral alcohol, both of which were retained (memorized) even after removal of the chiral alcohol. The chiral stationary phase for high-performance liquid chromatography, prepared by coating the polymer with macromolecular helicity memory on silica gel, showed good chiral recognition ability towards various racemates.
