3223-70-9Relevant articles and documents
SYNTHESIS OF BROMOALLENE UNDER CONDITIONS OF PHASE-TRANSFER CATALYSIS
Kurginyan, K. A.,Arakelova, S. V.,Kalaidzhyan, A. E.
, p. 2127 - 2130 (2007/10/02)
A new method was developed for the production of bromoallene by the dehydrobromination of 1,2,3-tribromopropane under the conditions of phase-transfer catalysis.It was shown that the bromoallene is produced as a result of the isomerization of the initially formed propargyl bromide.During the dehydrohalogenation of 2-bromo-3-chloro-1-propene, bromoallene, i.e.; the product from rearrangement with participation of the bromine atom, is formed in addition to propargyl chloride and chloroallene.