32135-18-5

Basic information

• Product Name: Diethyl-(1-methyl-1-phenyl-ethoxy)-silane
• Synonyms: Diethyl-(1-methyl-1-phenyl-ethoxy)-silane
• CAS NO: 32135-18-5
• Molecular Weight: 222.403
• Mol File: 32135-18-5.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Diethyl-(1-methyl-1-phenyl-ethoxy)-silane(CAS DataBase Reference)
• NIST Chemistry Reference: Diethyl-(1-methyl-1-phenyl-ethoxy)-silane(32135-18-5)
• EPA Substance Registry System: Diethyl-(1-methyl-1-phenyl-ethoxy)-silane(32135-18-5)

Safety Data

• Hazardous Substances Data: 32135-18-5(Hazardous Substances Data)

Upstream product

• 542-91-6 H₂SiEt₂ 
• 617-94-7 1-methyl-1-phenylethyl alcohol 

Relevant articles and documents

Silylation reactions on nanoporous gold: Via homolytic Si-H activation of silanes

Si-H bond activation is an important process implicated in many useful synthetic applications including silylation and transfer hydrogenation reactions. Herein we discovered homolytic activation of Si-H bonds on the surface of nanoporous gold (NPG), forming hydrogen radicals and [Au]-[Si] intermediates. By virtue of this new reactivity, we achieved highly selective mono and sequential alcoholysis of dihydrosilane. In addition, the amphiphilic nature of the [Au]-[Si] intermediate allows for a new bis-silylation reaction of cyclic ethers. The present work showcased that the surface reactivity of nanocatalysts may provide exciting opportunity for new reaction discovery.