31930-96-8Relevant articles and documents
Structural Characterization of 11-Ethyl-6,11-Dihydro-5H-Dibenzo[b,e]Azepine
Delgado,Osal,Mora,González,Palma,Bahsas
, p. 1210 - 1214 (2018/12/10)
The title compound C16H17N, a potential pharmaceutical agent, crystallizes in the monoclinic P21/n space group with unit cell parameters a = 9.911(7) ?, b = 5.542(3) ?, c = 23.245(16) ?, β = 96.25(2)°. The dibenzazepine ri
Highly efficient and regioselective allylic amination of allylic alcohols catalyzed by [Mo3PdS4] cluster
Tao, Yinsong,Zhou, Yuhan,Qu, Jingping,Hidai, Masanobu
experimental part, p. 1982 - 1984 (2010/06/21)
A highly efficient and regioselective allylation reaction of amines with allylic alcohols under mild conditions catalyzed by the cubane-type sulfido cluster [(Cp*Mo)3S4Pd(dba)][PF6] with H3BO3 as an additive has been developed. A variety of amines and allylic alcohols are investigated, and in the case of allylic alcohols bearing substituents at either α- or γ-position only linear allylic amination products are obtained.
Sequential amino-Claisen rearrangement/intramolecular 1,3-dipolar cycloaddition/reductive cleavage approach to the stereoselective synthesis of cis-4-hydroxy-2-aryl-2,3,4,5-tetrahydro-1(1H)-benzazepines
Ayala, Sandra Liliana Gómez,Stashenko, Elena,Palma, Alirio,Bahsas, Alí,Amaro-Luis, Juan Manuel
, p. 2275 - 2277 (2007/10/03)
A novel stereoselective synthesis of cis-2-aryl-4-hydroxy-2,3,4,5- tetrahydro-1-benzazepines from N-allylanilines utilizing aromatic amino-Claisen rearrangement and intramolecular 1,3-dipolar cycloaddition methodologies is described. This sequence involve