282717-26-4

Basic information

• Product Name: Ir(H)2((C₆H₅)NC(NHC₆H₅)NC₆H₅)(P(C₆H₅)3)2
• CAS NO: 282717-26-4
• Molecular Weight: 1005.17
• Mol File: 282717-26-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Ir(H)2((C₆H₅)NC(NHC₆H₅)NC₆H₅)(P(C₆H₅)3)2(CAS DataBase Reference)
• NIST Chemistry Reference: Ir(H)2((C₆H₅)NC(NHC₆H₅)NC₆H₅)(P(C₆H₅)3)2(282717-26-4)
• EPA Substance Registry System: Ir(H)2((C₆H₅)NC(NHC₆H₅)NC₆H₅)(P(C₆H₅)3)2(282717-26-4)

Safety Data

• Hazardous Substances Data: 282717-26-4(Hazardous Substances Data)

Upstream product

• 101-01-9 N,N',N''-triphenylguanidine 

Relevant articles and documents

N,N',N''-Triphenylguanidinate(-1) complexes of ruthenium, osmium and iridium: Synthesis and X-ray crystal structures

N,N',N'-Triphenylguanidine (TpgH) reacts with [Ru(H)2(CO)(PPh3)3] in refluxing toluene and with [Os(H)2(CO)(PPh3)3] in refluxing o-xylene to yield the guanidinate(-1) complexes [RuH(Tpg)(CO)(PPh3)2] (1) and [Os(Tpg)2(CO)(PPh3)] (2), respectively. The reaction of TpgH with [RuCl2(PPh3)3] in refluxing toluene affords a new route to the known complex [Ru(Tpg)2(CO)(PPh3)] (3). Finally the reaction of mer-[Ir(H)3(PPh3)3] with TpgH in refluxing toluene yields the iridium(III) dihydride complex [Ir(H)2(Tpg)(PPh3)2] (4). X-ray crystal structure determinations are reported for (1) and (4). (C) 2000 Elsevier Science S.A.