27798-45-4 Usage
Description
3-(4-TERT-BUTYLPHENYL)-1-PROPENE, with the chemical formula C13H18, is an organic compound belonging to the alkene class. It features a benzene ring with a tert-butyl group attached to the fourth carbon atom and a propene group connected to the first carbon atom. 3-(4-TERT-BUTYLPHENYL)-1-PROPENE is known for its role in the synthesis of polymers, plastics, and other organic compounds, as well as serving as a reagent in various organic chemistry reactions and a precursor to a range of chemicals. Due to its potential hazards, it is crucial to handle 3-(4-TERT-BUTYLPHENYL)-1-PROPENE with care and follow safety guidelines.
Uses
Used in Polymer and Plastics Industry:
3-(4-TERT-BUTYLPHENYL)-1-PROPENE is used as a monomer in the production of polymers and plastics for its ability to contribute to the formation of long-chain molecules that possess specific properties required in various applications.
Used in Organic Synthesis:
3-(4-TERT-BUTYLPHENYL)-1-PROPENE is used as a reagent in organic chemistry reactions, facilitating the synthesis of a variety of organic compounds due to its reactive alkene functional group and the presence of the tert-butylphenyl moiety.
Used in Chemical Intermediates Production:
As a precursor, 3-(4-TERT-BUTYLPHENYL)-1-PROPENE is utilized in the synthesis of other chemicals, playing a crucial role in the creation of intermediates that are vital for the production of pharmaceuticals, agrochemicals, and other specialty chemicals.
Check Digit Verification of cas no
The CAS Registry Mumber 27798-45-4 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 2,7,7,9 and 8 respectively; the second part has 2 digits, 4 and 5 respectively.
Calculate Digit Verification of CAS Registry Number 27798-45:
(7*2)+(6*7)+(5*7)+(4*9)+(3*8)+(2*4)+(1*5)=164
164 % 10 = 4
So 27798-45-4 is a valid CAS Registry Number.
InChI:InChI=1/C13H18/c1-5-6-11-7-9-12(10-8-11)13(2,3)4/h5,7-10H,1,6H2,2-4H3
27798-45-4Relevant articles and documents
Manganese catalyzed dehydrogenative silylation of alkenes: Direct access to allylsilanes
Wu, Shang,Zhang, Ying,Jiang, Hongyan,Ding, Ning,Wang, Yanbin,Su, Qiong,Zhang, Hong,Wu, Lan,Yang, Quanlu
supporting information, (2020/06/03)
Dehydrogenative silylation of alkenes with silanes to produce allylsilanes is achieved through manganese catalysis with a wide scope of substrate tolerance. This transformation involves silane radicals initiated by manganese complex without additional oxidant additives. It offers a general, convenient and practical protocol with excellent functional group compatibility and gram-scale capacity for the modular synthesis of allylsilanes.
Palladium-catalyzed tandem isomerization/hydrothiolation of allylarenes
Kathe, Prasad M.,Fleischer, Ivana
supporting information, p. 2213 - 2217 (2019/03/26)
Herein we report a tandem olefin migration/hydrothiolation of allyl benzenes facilitated by an in situ generated palladium hydride. A catalyst system composed of palladium acetate and bidentate ligand dtbpx (1,2-bis(di-tert-butylphosphinomethyl)benzene in the presence of catalytic amounts of triflic acid led to the tandem transformation, which furnished benzylic thioethers. The reaction exhibits high regioselectivity and can be conducted under mild conditions. The robustness of the catalyst is displayed through reactions with coordinating thiols.
Carbonylative Transformation of Allylarenes with CO Surrogates: Tunable Synthesis of 4-Arylbutanoic Acids, 2-Arylbutanoic Acids, and 4-Arylbutanals
Wu, Fu-Peng,Li, Da,Peng, Jin-Bao,Wu, Xiao-Feng
supporting information, p. 5699 - 5703 (2019/08/01)
In this Communication, procedures for the selective synthesis of 4-arylbutanoic acids, 2-arylbutanoic acids, and 4-arylbutanals from the same allylbenzenes have been developed. With formic acid or TFBen as the CO surrogate, reactions proceed selectively and effectively under carbon monoxide gas-free conditions.
