27644-03-7Relevant articles and documents
Marvell,Almond
, p. 2777 (1979)
Catalytic asymmetric aldehyde prenylation and application in the total synthesis of (-)-rosiridol and (-)-bifurcadiol
Huang, Yi-Yong,Kalita, Subarna Jyoti,Li, Jing-Jie,Li, Wang-Lai,Schneider, Uwe,Zhang, Yu-Long,Zhao, Zhen-Ni
, p. 10030 - 10033 (2020/09/15)
Chiral phosphoric acid-catalyzed asymmetric aldehyde prenylation has been established using an α,α-dimethyl allyl boronic ester. The transformation provides expedient access to a wide array of aryl, heteroaryl, aryl-substituted alkenyl and primary and sec
Highly regioselective and chemoselective titanocene mediated Barbier-type allylation reactions
Morcillo, Sara P.,Martinez-Peragon, Angela,Jakoby, Verena,Mota, Antonio J.,Kube, Christian,Justicia, Jose,Cuerva, Juan M.,Gansaeuer, Andreas
supporting information, p. 2211 - 2213 (2014/02/14)
Titanocene carboxylate 1 is an excellent chemoselective reagent for unprecedented α-regioselective Barbier-type reactions. It constitutes the first titanocene(iii) able to tolerate epoxides and readily reduced carbonyl compounds, such as aromatic and α,β-unsaturated aldehydes. The Royal Society of Chemistry.