2700-84-7Relevant articles and documents
Synthetic utility of iodic acid in the oxidation of benzylic alcohols to aromatic aldehydes and ketones
Imai, Sho,Togo, Hideo
, p. 6948 - 6954 (2016/10/13)
Various primary and secondary benzylic alcohols were efficiently oxidized to aromatic aldehydes and aromatic ketones with iodic acid in DMF at 60?°C for 2?h and with iodic acid in the presence of TEMPO (5?mol?%) in DMF at room temperature, respectively. The former method was effective for the oxidation of sterically hindered alcohols at 60?°C and the latter method was effective for the oxidation of less sterically hindered alcohols at room temperature.
Direct, Low Temperature, in Situ Nucleophilic Aroylation with Aroyllithium Reagents
Seyferth, Dietmar,Hui, Richard C.,Wang, Wei-Liang
, p. 5843 - 5845 (2007/10/02)
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Acylierung von Aromaten mit Carbonsaeure-dihalogenphosphorsaeure-anhydriden
Effenberger, Franz,Koenig, Gerd,Klenk, Herbert
, p. 926 - 936 (2007/10/02)
Aryl ketones 4, 9 are formed in good yields without the addition of Friedel-Crafts catalysts from activated arenes (e. g. alkylbenzenes, anisole) and aryl- and alkylcarboxylic dihalophosphoric anhydrides 1, 2, and 7, 8, respectively.The anhydrides 7, 8 may be prepared in situ by mixing the respective carboxylic and dihalophosphoric anhydrides.This procedure is especially advantageous in care of the less stable compounds.