269719-26-8Relevant articles and documents
Synthesis of 1-p-tolysulfinyl-1,3-dienes by intramolecular heck reactions
Mar Segorbe,Adrio, Javier,Carretero, Juan C.
, p. 1983 - 1986 (2007/10/03)
The first examples of the synthesis of 1,3-dienyl sulfoxides by Heck reactions are described. Both racemic and enantiomerically pure exocyclic 1- p-tolylsulfinyl-1,3-dienes 1 are readily prepared by the intramolecular Heck reaction of their corresponding vinyl iodides in the presence of Pd(OAc)2 as catalyst and Ag2CO3 as base. (C) 2000 Elsevier Science Ltd.