25699-93-8

Basic information

• Product Name: Benzonitrile, 2-(1H-benzimidazol-1-yl)-
• CAS NO: 25699-93-8
• Molecular Formula: C14H9N3
• Molecular Weight: 219.246
• Mol File: 25699-93-8.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: Benzonitrile, 2-(1H-benzimidazol-1-yl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzonitrile, 2-(1H-benzimidazol-1-yl)-(25699-93-8)
• EPA Substance Registry System: Benzonitrile, 2-(1H-benzimidazol-1-yl)-(25699-93-8)

Safety Data

• Hazardous Substances Data: 25699-93-8(Hazardous Substances Data)

Upstream product

• 51-17-2 benzoimidazole 
• 2042-37-7 o-cyanobromobenzene 
• 172732-52-4 o-cyanophenylboronic acid-1,3-propylene glycol ester 
• 394-47-8 2-fluorobenzonitrile 
• 873-32-5 2-Chlorobenzonitrile 

Downstream Products

• 946147-47-3 2-(2-bromo-1H-benzo[d]imidazol-1-yl)benzonitrile 
• 29003-05-2 2-(benzimidazol-1'-yl)benzoic acid 

Relevant articles and documents

N-Arylation of nitrogen containing heterocycles with aryl halides using copper nanoparticle catalytic system

Cu nanoparticles promoted N-arylation of NH-heterocycles with aryl halides is an effective and inexpensive method. In this synthetic protocol, good to excellent yields are obtained. Both aryl iodide and aryl bromide are compatible with the reaction conditions.

METAL COMPLEXES OF CYCLOMETALLATED IMIDAZO[1,2-f]PHENANTHRIDINE AND DIIMIDAZO[1,2-A:1',2'-C]QUINAZOLINE LIGANDS AND ISOELECTRONIC AND BENZANNULATED ANALOGS THEREOF

The present invention refers to-imidazo [1,2-f] the dee trillion which gets torn phenylphenanthridines and [1,2-a:1 ', 2' -c] quinazoline ligands, or its isoelectronic characteristic and or phosphor including analogue relates to compounds including metal complex. Furthermore, the present invention refers to these compounds including relates organic light emitting diode devices. (by machine translation)

Bis(μ-iodo)bis((-)-sparteine)dicopper(I): versatile catalyst for direct N-arylation of diverse nitrogen heterocycles with haloarenes

The easy-to-prepare dimeric bis(μ-iodo)bis((-)-sparteine)dicopper(I) complex is shown to be a versatile catalyst for N-arylation of number of NH-heterocycles with structurally divergent aryl halides including activated aryl chloride substrates under mild conditions. The DFT studies not only provide structural insights into square-pyramidal Cu(III) intermediate complexes derived from (-)-sparteine, but also highlight the important role of sterically demanding (-)-sparteine ligand framework in promoting activation of aryl-chlorine bonds for N-arylation of imidazoles.