215438-84-9

Basic information

• Product Name: methyl diphenylsulfonium triflate
• Synonyms: methyl diphenylsulfonium triflate
• CAS NO: 215438-84-9
• Molecular Weight: 364.41
• Mol File: 215438-84-9.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: methyl diphenylsulfonium triflate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl diphenylsulfonium triflate(215438-84-9)
• EPA Substance Registry System: methyl diphenylsulfonium triflate(215438-84-9)

Safety Data

• Hazardous Substances Data: 215438-84-9(Hazardous Substances Data)

Upstream product

• 66003-78-9 triphenylsulfonium trifluoromethanesulfonate 
• 945-51-7 1,1'-sulfinylbisbenzene 
• 1493-13-6 trifluorormethanesulfonic acid 
• 139-66-2 diphenyl sulfide 
• 109-94-4 formic acid ethyl ester 
• 141-78-6 ethyl acetate 

Downstream Products

• 105229-70-7 methyldiphenylsulfonium trifluoromethanesulfonate 
• 7380-78-1 4-(phenylethynyl)anisole 
• 37696-01-8 1-methoxy-3-(phenylethynyl)benzene 
• 41398-67-8 2-phenylethynylanisole 
• 1034142-69-2 1-ethoxy-4-(phenylethynyl)benzene 
• 139-66-2 diphenyl sulfide 
• 501-65-5 diphenyl acetylene 
• 3287-02-3 4-(phenylethynyl)toluene 
• 29778-26-5 [(4-tert-butylphenyl)ethynyl]benzene 
• 5172-02-1 1-chloro-4-(2-phenylethynyl)benzene 
• 4044-57-9 1-phenylethynyl-naphthalene 
• 40164-53-2 1,4-diphenyl-1-butyne 
• 1504-58-1 3-Phenyl-2-propyn-1-ol 
• 73922-81-3 4-phenyl-but-3-yn-2-ol 

Relevant articles and documents

Sonogashira reaction using arylsulfonium salts as cross-coupling partners

Triarylsulfonium, alkyl- and fluoroalkyl(diaryl)-sulfonium, and aryl(dialkyl)sulfonium triflates are successfully used as a new family of cross-coupling participants in the Sonogashira reaction as aryldiazonium, diaryliodonium, and tetraphenylphosphonium salts. It was found that terminal alkynes reacted mildly with triarylsulfonium or (2,2,2-trifluoroethyl)diphenylsulfonium triflate at room temperature under Pdand Cu-cocatalysis to give the corresponding arylalkynes in up to >99% yield. This protocol represents the first use of arylsulfonium salts as cross-coupling partners in the Pd/Cu-catalyzed Sonogashira reaction.

Superacidified reaction of sulfides and esters for the direct synthesis of sulfonium derivatives

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