204381-17-9Relevant articles and documents
Total synthesis of spinosyn A. 1. Enantioselective construction of a key tricyclic intermediate by a multiple configurational inversion scheme
Paquette, Leo A.,Gao, Zhongli,Ni, Zhijie,Smith, Graham F.
, p. 2543 - 2552 (2007/10/03)
The condensation of (+)-7,7-dimethoxynorbomen-2-one with the cerium reagent derived from enantiopure bromide (+)-11 gives rise to an exo carbinol, which readily undergoes highly stereocontrolled anionic oxy-Cope rearrangement. Conversion of the resulting