2034-53-9

Basic information

• Product Name: apocamphane
• Synonyms: apocamphane;7,7-Dimethylbicyclo[2.2.1]heptane;Apobornylane;α-Fenchocamphorane
• CAS NO: 2034-53-9
• Molecular Formula: C₉H₁₆
• Molecular Weight: 0
• Mol File: 2034-53-9.mol
• Article Data: 4

Chemical Properties

• Boiling Point: 140.4°C at 760 mmHg
• Flash Point: 23.4°C
• Appearance: /
• Density: 0.864g/cm³
• Vapor Pressure: 7.67mmHg at 25°C
• Refractive Index: 1.464
• CAS DataBase Reference: apocamphane(CAS DataBase Reference)
• NIST Chemistry Reference: apocamphane(2034-53-9)
• EPA Substance Registry System: apocamphane(2034-53-9)

Safety Data

• Hazardous Substances Data: 2034-53-9(Hazardous Substances Data)

Usage

InChI:InChI=1/C9H16/c1-9(2)7-3-4-8(9)6-5-7/h7-8H,3-6H2,1-2H3

Upstream product

• 69855-37-4 7-Methylbicyclo<2.2.1>heptan-7-carbonaldehyd 
• 51689-30-6 7,7-dibromoborbornane 
• 77-78-1 dimethyl sulfate 
• 22768-98-5 2-chloro-7,7-dimethyl-norbornane 
• 6541-60-2 apobornene 
• 37609-61-3 7-methyl-2-oxobicyclo[2.2.1]heptane-7-carboxylic acid 
• 30244-06-5 2-exo-Hydroxy-7-anti-methylbicyclo<2.2.1>heptan-7-syn-carbonsaeure-γ-lacton 
• 69855-36-3 7-methylbicyclo[2.2.1]heptane-7-carbonyl chloride 
• 69855-35-2 7-methyl-7-carboxynorbornane 
• 82478-41-9 5-methyltetracyclo<3.3.0.0^2,4.0^3,6>oct-7-ene 
• 40550-42-3 7,7-dimethyl-norbornan-2-one-hydrazone 
• 141-52-6 sodium ethanolate 
• 110977-32-7 7,7-dimethylbicyclo<2.2.1>heptane-1-carbaldehyde 

Relevant articles and documents

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Preparation and Some Properties of 7,7-Dilithionorbornane

7,7-Dilithionorbornane 4a is formed from 7,7-dibromonorbornane 4b by reduction with 4.5 equiv of lithium p,p'-di-tert-butylbiphenyl at -100 deg C, at which temperature it adds to ethylene.On warming it rearranges to 1-lithio-5-(2-lithioethyl)cyclopentene 5.

SYNTHESIS OF TETRACYCLO2,4.03,6>OCT-7-ENE AND SOME OF ITS DERIVATIVES

A full account is given of the synthesis of the title compound, its 7,8-dihydro-analogue and of some of its derivatives.