19727-16-3Relevant articles and documents
Method for separating partial (meth)acrylated polyols and urethane-based materials functionalized with (meth)acrylate produced by the partial (meth)acrylated polyols
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Paragraph 0090-0097, (2020/06/04)
A method for separating a partial (meth)acrylated polyol of the present invention comprises the steps of: making a triol react with (meth)acrylate; firstly extracting by adding water to the partial (meth)acrylated polyol prepared from the reaction step; and secondly extracting by adding a solvent to a first aqueous phase which is separated from a first organic phase in the first extraction step. A urethane-based material functionalized with (meth)acrylate of the present invention can be prepared by the reaction of a partial (meth)acrylated polyol and isocyanate.(AA) Reaction of polio and (meth)acrylate (poll, mono-, and de-(meth)acrylated polyol)(BB) Water (25%, v/v) 10 times extraction(CC) First organic phase(DD) First aqueous phase(EE) Evaporation of drying (molecular) solvent(FF) Dichloromethane (25%, v/v) 3 times extraction(GG) De-(meth)acrylated polyol(HH) Second organic phase(II) Second aqueous phase(JJ) Evaporation of drying (molecular) solvent(KK) Mono-(meth)acrylated polyol(LL) Remaining polyolsCOPYRIGHT KIPO 2020
Adamantane derivatives and processes for the preparation thereof
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Page column 26-27, (2008/06/13)
Adamantane derivatives in which two (meth)acryloyloxyalkyl groups are bonded with an adamantane ring through ester groups, adamantane derivatives in which two adamantane rings are bonded through an alkylene group and two urethane bonds, which two adamantane rings each have a (meth)acryloyloxy group bonded thereto directly or through a coupling group, and adamantane derivatives each having a structure in which a group containing an adamantane ring hangs on the alkylene group of an alkylene glycol di(meth)acrylate. The compounds are useful as dental materials intermediates therefor, and as intermediates for optical materials such as lenses.