1927-61-3

Basic information

• Product Name: tetrahydro-2-(2-phenylethoxy)-2H-pyran
• Synonyms: tetrahydro-2-(2-phenylethoxy)-2H-pyran;2-(2-Phenylethoxy)tetrahydro-2H-pyran;2-(Phenethyloxy)tetrahydro-2H-pyran;2-Phenylethyl(tetrahydro-2H-pyran-2-yl) ether;Phenethyl(tetrahydro-2H-pyran-2-yl) ether;Phenethyltetrahydro-2H-pyran-2-yl ether
• CAS NO: 1927-61-3
• Molecular Formula: C₁₃H₁₈O₂
• Molecular Weight: 206.28082
• EINECS: 217-666-5
• Mol File: 1927-61-3.mol
• Article Data: 62

Chemical Properties

• Boiling Point: 300.6°C at 760 mmHg
• Flash Point: 114.5°C
• Appearance: /
• Density: 1.03g/cm³
• Vapor Pressure: 0.00199mmHg at 25°C
• Refractive Index: 1.519
• CAS DataBase Reference: tetrahydro-2-(2-phenylethoxy)-2H-pyran(CAS DataBase Reference)
• NIST Chemistry Reference: tetrahydro-2-(2-phenylethoxy)-2H-pyran(1927-61-3)
• EPA Substance Registry System: tetrahydro-2-(2-phenylethoxy)-2H-pyran(1927-61-3)

Safety Data

• Hazardous Substances Data: 1927-61-3(Hazardous Substances Data)

Usage

InChI:InChI=1/C13H18O2/c1-2-6-12(7-3-1)9-11-15-13-8-4-5-10-14-13/h1-3,6-7,13H,4-5,8-11H2

Upstream product

• 142-68-7 TETRAHYDROPYRANE 
• 60-12-8 2-phenylethanol 
• 126680-79-3 tert-butyldimethyl((tetrahydro-2H-pyran-2-yl)oxy)silane 
• 694-54-2 tetrahydro-2H-2-pyranol 
• 110-87-2 3,4-dihydro-2H-pyran 
• 14629-58-4 trimethyl(phenethyloxy)silane 
• 143888-88-4 2-(2-bromophenyl)ethyl tetrahydro-2H-pyran-2-yl ether 
• 69161-61-1 2-(prop-2-en-1-yloxy)oxane 

Downstream Products

• 103-45-7 acetic acid phenethyl ester 
• 104-62-1 formic acid phenethyl ester 
• 645-59-0 dihydrocinnamonitrile 
• 6926-44-9 phenethyl azide 
• 52767-51-8 (±)-2-phenethoxytetrahydrofuran 
• 4412-39-9 (2,2-dichloroethyl)benzene 
• 1943-82-4 phenethyl isocyanate 
• 5654-72-8 2-phenylethyl thiocyanate 
• 122-78-1 phenylacetaldehyde 
• 94-47-3 2-Phenylethyl benzoate 
• 20965-36-0 2-(phenylthio)tetrahydro-2H-pyran 
• 83711-12-0 5,5-bis(phenylthio)-1-pentanol 
• 60-12-8 2-phenylethanol 
• 133885-11-7 5-Phenethyloxy-pentan-1-ol 

Relevant articles and documents

Bronsted acidic ionic liquids: Fast, mild, and efficient catalysts for solvent-free tetrahydropyranylation of alcohols

Bronsted acidic ionic liquids as efficient and reusable catalysts for the protection of alcohols as tetrahydropyranyl (THP) ethers under solvent-free conditions at room temperature was investigated. Good to excellent yields were obtained at a faster rate over [BMIm][HSO4] or [BMIm][H2PO4]. Copyright Taylor & Francis, Inc.

Metal-free tetrahydrofuranylation of alcohols with tertbutyl nitrite

Metal-free tetrahydrofuranylation of alcohols in the presence of tertbutyl nitrite is described, providing a facile and green route for the protection of hydroxy groups. Mechanistic studies demonstrate that this transformation proceeds in a radical way, and involves alkyl nitrite of corresponding alcohol as the key intermediate.

Direct Conversion of TMS-ethers to THP-ethers Catalyzed by {[K.18-Crown-6]Br3}n

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