1855-47-6

Basic information

• Product Name: 2-ISOPROPENYLNAPHTHALENE
• Synonyms: 1-(1-methylethenyl)naphthalene;1-Isopropenylnaphthalene;1-isopropenyl-naphthalene;isopropenylnaphthalene;naphthalene,1-(1-methylethenyl);2-ISOPROPENYLNAPHTHALENE;2-ISOPROPENYLNAPHTHALENE 98+%
• CAS NO: 1855-47-6
• Molecular Formula: C₁₃H₁₂
• Molecular Weight: 168.23
• Mol File: 1855-47-6.mol
• Article Data: 41

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 2-ISOPROPENYLNAPHTHALENE(CAS DataBase Reference)
• NIST Chemistry Reference: 2-ISOPROPENYLNAPHTHALENE(1855-47-6)
• EPA Substance Registry System: 2-ISOPROPENYLNAPHTHALENE(1855-47-6)

Safety Data

• Hazardous Substances Data: 1855-47-6(Hazardous Substances Data)

Usage

InChI:InChI=1S/C13H12/c1-10(2)12-9-5-7-11-6-3-4-8-13(11)12/h3-9H,1H2,2H3

Upstream product

• 86-55-5 1-naphthalenecarboxylic acid 
• 75-24-1 trimethylaluminum 
• 3859-41-4 1,3-cyclopentadione 
• 463-49-0 1,2-propanediene 
• 123994-49-0 3,4-dihydro-1-naphthyl triflate 
• 70123-52-3 bis-(1-[1]naphthyl-ethylidene)-hydrazine 
• 90-14-2 1-Iodonaphthalene 
• 288321-56-2 1-Methyl-1-(1'-methylethenyl)silacyclobutane 
• 50443-88-4 9-dimethyl-1,4,5,8-tetrahydro-4a,8a-methanonaphthalene 
• 90-11-9 1-Bromonaphthalene 
• 941-98-0 1'-naphthacetophenone 
• 67-71-0 dimethylsulfone 
• 4780-79-4 1-naphthalene methanol 
• 879-18-5 naphthalene-1-carbonic acid chloride 

Downstream Products

• 91-20-3 naphthalene 
• 6158-45-8 1-isopropylnaphthalene 
• 941-98-0 1'-naphthacetophenone 
• 860596-08-3 2-(4-isopropyl-[1]naphthoyl)-benzoic acid 
• 1417657-58-9 1-benzyl-3-(2-(naphthalen-1-yl)propan-2-yl)-1H-indole 
• 1415643-35-4 1-(3-tosylprop-1-en-2-yl)naphthalene 
• 203-64-5 4H-Cyclopenta[def]phenanthrene 

Relevant articles and documents

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Dehydrohalogenation of haloalkylarenes in the synthesis of alkenylaromatic hydrocarbons

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1,3-Difunctionalization of β-alkyl nitroalkenes via combination of Lewis base catalysis and radical oxidation

Upon treatment with a Lewis base catalyst, β-alkyl-substituted nitroalkenes could be readily converted into allylic nitro compounds. Examples of either C-1 or C-3 functionalization methods have been reported through nitro-elimination, giving alkene products. In this work, successful 1,3-difunctionalization was achieved through a synergetic Lewis base catalysis and TBHP radical oxidation, giving vinylic alkoxyamines in good to excellent yields. This work further extended the general synthetic application of β-alkyl nitroalkenes.

The cascade coupling/iodoaminocyclization reaction of trifluoroacetimidoyl chlorides and allylamines: metal-free access to 2-trifluoromethyl-imidazolines

A metal-free cascade coupling/iodoaminocyclization reaction for the rapid assembly of 2-trifluoromethyl-imidazolines has been disclosed. The transformation applies readily accessible trifluoroacetimidoyl chlorides, allylamines andN-iodosuccinimides as the starting substrates, achieving an efficient and straightforward pathway to construct diverse imidazoline derivatives. Excellent efficiency of the reaction is observed (higher than 90% isolated yield for half of the examples), and the obtained imidazoline products bearing a pendent iodomethyl group could be easily transformed into other synthetically valuable compounds.