183-84-6Relevant articles and documents
New preparation of 1,2,4,5-tetraoxanes
Terent'ev,Kutkin,Starikova,Antipin,Ogibin,Nikishin
, p. 2356 - 2366 (2004)
A convenient procedure was developed for the synthesis of 1,2,4,5-tetraoxanes based on the reaction of gem-bishydroper-oxycycloalkanes with ketals and acetals catalyzed by boron trifluoride etherate, which makes it possible to prepare the target products
METHOD FOR MANUFACTURING ESTER
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Paragraph 0040 - 0046, (2013/08/28)
The present invention relates to a method for manufacturing an ester from a ketone or an aldehyde, which is a reactive substrate, by a Baeyer-Villiger oxidation reaction using hydrogen peroxide, and in this method, as a catalyst, M(BAr4)n, which is a metal borate, is used (M represents an alkali metal or an alkaline earth metal; Ar represents an aryl; and n is the same number as the valence of M). For example, when cyclohexanone was used as the reactive substrate, and Sr[B(3,5-CF3C6H3)4]2 was used as the catalyst, ε-caprolactone was obtained at an isolated yield of 82%.
Supported sulfonic acid as green and efficient catalyst for Baeyer-Villiger oxidation with 30% aqueous hydrogen peroxide
Piscopo, Calogero G.,Loebbecke, Stefan,Maggi, Raimondo,Sartori, Giovanni
experimental part, p. 1625 - 1629 (2010/10/01)
Silica-supported propylsulfonic acid is a very good heterogeneous catalyst for the Baeyer-Villiger oxidation of cyclic ketones to lactones with stoichiometric 30% aqueous hydrogen peroxide in 1,1,1,3,3,3-hexafluoro-2- propanol as solvent.