17993-73-6

Basic information

• Product Name: Ethanone, 1-phenyl-, O-(trimethylsilyl)oxime
• CAS NO: 17993-73-6
• Molecular Formula: C11H17NOSi
• Molecular Weight: 207.348
• Mol File: 17993-73-6.mol
• Article Data: 8

Chemical Properties

• CAS DataBase Reference: Ethanone, 1-phenyl-, O-(trimethylsilyl)oxime(CAS DataBase Reference)
• NIST Chemistry Reference: Ethanone, 1-phenyl-, O-(trimethylsilyl)oxime(17993-73-6)
• EPA Substance Registry System: Ethanone, 1-phenyl-, O-(trimethylsilyl)oxime(17993-73-6)

Safety Data

• Hazardous Substances Data: 17993-73-6(Hazardous Substances Data)

Upstream product

• 75-77-4 chloro-trimethyl-silane 
• 613-91-2 acetophenone oxime 
• 50314-86-8 acetophenone oxime 
• 98-86-2 acetophenone 
• 3385-94-2 hexamethyldisilathiane 
• 999-97-3 1,1,1,3,3,3-hexamethyl-disilazane 
• 4039-32-1 lithium hexamethyldisilazane 

Downstream Products

• 103-84-4 Acetanilid 
• 2627-86-3 (S)-1-phenyl-ethylamine 
• 3886-69-9 (R)-1-phenyl-ethyl-amine 
• 13599-24-1 ethyl 3-phenylisoxazole-5-carboxylate 
• 169271-95-8 ethyl 4-phenyl-4-hydroximino-2-oxobutyrate 

Relevant articles and documents

Selective silylation of alcohols, phenols and oximes using N-chlorosaccharin as an efficient catalyst under mild and solvent-free conditions

Efficient silylation of OH group in alcohols, phenols and oximes is described using a catalytic amount of N-chlorosaccharin and hexamethyldisilazane (HMDS) under mild and solvent-free conditions. This silylation reaction can be carried out with excellent and interesting various selectivities.

Alumina perchloric acid (Al2O3-HClO4) as an efficient heterogeneous catalyst for modified preparation of trimethylsilyl ethers

A highly efficient and mild procedure for the trimethylsilylation of a wide variety of alcohols, including primary, benzylic, secondary, hindered secondary, tertiary, phenols, and oximes with hexamethyldisilazane (HMDS) using alumina perchloric acid (Al2O3-HClO4) as recyclable heterogeneous catalyst in excellent yields with short reaction times (3-65 min) under ambient conditions is described. Copyright Taylor & Francis Group, LLC.

The catalytic Friedel-Crafts acylation reaction and the catalytic Beckmann rearrangement promoted by a Gallium(III) or an antimony(V) cationic species

The catalytic Friedel-Crafts acylation reaction and the catalytic Beckmann rearrangement are successfully carried out by using the active cationic species dichlorogallium(III) perchlorate and tetrachloroantimonium(V) hexafluoroantimonate(V), respectively, which were generated in situ from appropriate silver, gallium(III) or antimony(V) salts.