168911-80-6

Basic information

• Product Name: [Pt(η(2)-CH2=CHC6H4F-3)(Bu(t)2P(CH2)3PBu(t)2)]
• CAS NO: 168911-80-6
• Molecular Weight: 649.712
• Mol File: 168911-80-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [Pt(η(2)-CH2=CHC6H4F-3)(Bu(t)2P(CH2)3PBu(t)2)](CAS DataBase Reference)
• NIST Chemistry Reference: [Pt(η(2)-CH2=CHC6H4F-3)(Bu(t)2P(CH2)3PBu(t)2)](168911-80-6)
• EPA Substance Registry System: [Pt(η(2)-CH2=CHC6H4F-3)(Bu(t)2P(CH2)3PBu(t)2)](168911-80-6)

Safety Data

• Hazardous Substances Data: 168911-80-6(Hazardous Substances Data)

Upstream product

• 66467-57-0 {PtCl₂(dbpp)} 
• 350-51-6 3-fluorostyrene 

Relevant articles and documents

Effect of Phenyl Substitution on Bonding in η3-Benzyl Complexes of Platinum

Reaction of the platinum(0) styrene complexes 2-CH2=CHC6H4X)> 1a-1f (X = Br-3, Br-4, Me-4, F-4, F-3 or MeO-4) with HBF4 in diethyl ether afforded the η3-methylbenzyl complexes 3-MeCHC6H4X)> 2a-2f.The effect of phenyl substitution on the asymmetry of the η3-methylbenzyl interaction was measured by 31P- NMR spectroscopy and it was found that, in general, the more electron releasing the substituent, X, the more asymmetric is the bonding.Complexes 2a-2f lose styrene reversibly to form the hydride-bridged dinuclear platinum complex 2>2.Displacement of styrenes from 2a-2f by ethene and bicyclohept-2-ene affords known complexes stabilized by a three-centre, two-electron (agostic) bond.