1610422-31-5

Basic information

• Product Name: (E)-n-butyl 2-(6-benzyl-7-oxo-6,7-dihydro-5H-pyrrolo[3,4-b]pyridin-5-ylidene)acetate
• Synonyms: (E)-n-butyl 2-(6-benzyl-7-oxo-6,7-dihydro-5H-pyrrolo[3,4-b]pyridin-5-ylidene)acetate
• CAS NO: 1610422-31-5
• Molecular Weight: 336.39
• Mol File: 1610422-31-5.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (E)-n-butyl 2-(6-benzyl-7-oxo-6,7-dihydro-5H-pyrrolo[3,4-b]pyridin-5-ylidene)acetate(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-n-butyl 2-(6-benzyl-7-oxo-6,7-dihydro-5H-pyrrolo[3,4-b]pyridin-5-ylidene)acetate(1610422-31-5)
• EPA Substance Registry System: (E)-n-butyl 2-(6-benzyl-7-oxo-6,7-dihydro-5H-pyrrolo[3,4-b]pyridin-5-ylidene)acetate(1610422-31-5)

Safety Data

• Hazardous Substances Data: 1610422-31-5(Hazardous Substances Data)

Upstream product

• 18904-38-6 N-benzyl-2-pyridinecarboxamide 
• 141-32-2 acrylic acid n-butyl ester 
• 98-98-6 2-Picolinic acid 
• 100-46-9 benzylamine 
• 29745-44-6 pyridine-2-carbonyl chloride 

Relevant articles and documents

Rh(III)-catalyzed cascade oxidative olefination/cyclization of picolinamides and alkenes via C-H activation

Rh(III)-catalyzed cascade oxidative alkenylation/cyclization of picolinamides and alkenes to furnish pyrido pyrrolone derivatives is described, in which three C-H bonds and one N-H bond broke, while one C-C bond and one C-N bond formed. The reaction proceeded with high yield and high regioselectivity and stereoselectivity. Moreover, copper acetate can also be used in catalytic amounts with O2 serving as the terminal oxidant.